Competing forces in the interaction of polyelectrolytes with charged interfaces

被引：26
作者：
Faraudo, Jordi [1 ]
Martin-Molina, Alberto [2 ]
机构：
[1] Inst Ciencia Mat Barcelona ICMAB CSIC, E-08193 Bellaterra, Spain
[2] Univ Granada, Dept Fis Aplicada, Grp Fis Fluidos & Biocoloides, Granada, Spain
来源：
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE | 2013年 / 18卷 / 06期
关键词：
Polyelectrolytes; Adsorption; Charge reversal; Like-charge attraction; Molecular dynamics simulations; Monte Carlo simulations; Hydrogen bonding; Hydrophobic effect; MONTE-CARLO; PHOSPHATIDIC-ACID; ADSORPTION; DNA; SURFACES; SIMULATIONS; INVERSION; COMPLEXATION; ELECTROSTATICS; CONDENSATION;
D O I：
10.1016/j.cocis.2013.10.001
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this review, we discuss the competition of non-DLVO forces in the adsorption of polyelectrolytes onto charged surfaces. We consider two particularly illustrative problems, namely the adsorption of polyelectrolytes onto similarly charged surfaces and the reversal of surface charge by adsorption of polyelectrolytes. Emphasis is made on how simulation results help to understand relevant experimental situations. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：517 / 523
页数：7
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