Synthesis and structural characterization of RE6Cd23T (RE=La-Gd; T=Sn, Sb, Pb, and Bi)

被引：2

作者：

Desroches, Griffen ^{[1
]}

Bobev, Svilen ^{[1
]}

机构：

[1] Univ Delaware, Dept Chem & Biochem, 304A Drake Hall, Newark, DE 19716 USA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2017年 / 246卷

关键词：

Intermetallic compounds; Crystal structure; Lanthanides; Cadmium; CRYSTAL-CHEMISTRY; LA; ND; PHASES; PR; GE; SN; SI; SM;

D O I：

10.1016/j.jssc.2016.11.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthetic methods and structural characterization are reported for 11 novel ternary compounds with the general formula RE6Cd23T (RE=La Gd; T=Sn, Sb, Pb, and Bi). Their crystal structures, as revealed by single crystal and powder X-ray diffraction, are of the cubic Zr6Zn23Si structure type (cF120, Fm (3) over barm, Z=4), a filled version of the Th6Mn23 system. No Cd-containing rare-earth metal binaries are known to form with this structure, but the inclusion of small amounts of a third element allows the formation of the interstitially stabilized ternary structures. Temperature dependent de magnetization measurements confirm local-moment magnetism due to RE3+ ground states for Ce, Pr, and Nd.

引用

页码：203 / 208

页数：6