Aqua(3-formyl-2-oxidobenzoato-κ2O1,O2)(1,10-phenanthroline-κ2N,N′)copper(II) dimethylformamide solvate

被引:6
作者
Yu, Zhao-Wen [1 ]
Chang, Ling [1 ]
Song, Peng [1 ]
He, Min-Hui [1 ]
机构
[1] Henan Univ, Coll Chem & Chem Engn, Inst Mol & Crystal Engn, Kaifeng 475001, Henan, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
D O I
10.1107/S1600536809011659
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the structure of the title complex, [Cu(C8H4O4)(C12H8N2)(H2O)]center dot C3H7NO, the Cu-II ion is pentacoordinated in a distorted square-pyramidal geometry by two O atoms of a 3-formyl-2-oxidobenzoate dianion and two N atoms of a 1,10-phenanthroline ligand occupying the basal plane and a water O atom located at the apical site. The structure displays O-H center dot center dot center dot O hydrogen bonding and intermolecular pi-pi stacking interactions between 1,10-phenantroline ligands [interplanar distance of 3.448 (5) angstrom].
引用
收藏
页码:M485 / U252
页数:11
相关论文
共 3 条
  • [1] Bruker, 2005, APEX2 SAINT SADABS
  • [2] A short history of SHELX
    Sheldrick, George M.
    [J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122
  • [3] Aqua(3-formyl-2-oxidobenzoato-κ2O1,O2)(1,10-phenanthroline-κ2N,N′) copper(II) methanol solvate
    Zhang, Wu
    Cui, Qingxia
    Chang, Ling
    Yu, Zhaowen
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M294 - U281