A porous metal-metalloporphyrin framework featuring high-density active sites for chemical fixation of CO2 under ambient conditions

被引：206
作者：
Gao, Wen-Yang [1 ]
Wojtas, Lukasz [1 ]
Ma, Shengqian [1 ]
机构：
[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 40期
关键词：
ORGANIC FRAMEWORKS; CATALYTIC-ACTIVITY; CRYSTAL-STRUCTURE; STYRENE OXIDE; PORPHYRIN; PHOTOSYNTHESIS; CYCLOADDITION; CARBONATE; SOLIDS;
D O I：
10.1039/c3cc47542e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Self-assembly of the custom-designed octatopic porphyrin ligand of tetrakis(3,5-dicarboxybiphenyl) porphine with the in situ generated Cu-2(CO2)(4) paddlewheel moieties afforded a porous metalmetalloporphyrin framework, MMPF-9, which features a high density of Cu(II) sites confined within nanoscopic channels and demonstrates excellent performances as a heterogeneous Lewis-acid catalyst for chemical fixation of CO2 to form carbonates at room temperature under 1 atm pressure.
引用
收藏
页码：5316 / 5318
页数：3
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