Structural and optical properties of Ga-doped CdO nanocrystalline thin films

被引:47
作者
Thambidurai, M. [1 ]
Muthukumarasamy, N. [2 ]
Ranjitha, A. [2 ]
Velauthapillai, Dhayalan [3 ]
机构
[1] Seoul Natl Univ, Global Frontier Ctr Multiscale Energy Syst, Dept Elect & Comp Engn, Seoul 151744, South Korea
[2] Coimbatore Inst Technol, Dept Phys, Coimbatore, Tamil Nadu, India
[3] Bergen Univ Coll, Fac Engn & Business Adm, Bergen, Norway
关键词
Semiconductor; Thin films; Ga-doped CdO; Sol-gel method; Optical properties; CADMIUM-OXIDE;
D O I
10.1016/j.spmi.2015.08.020
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
In the present work, a systematic study has been carried out to understand the effect of gallium doping on the various properties of the CdO nanocrystalline thin films. Ga-doped CdO nanocrystalline thin films with different gallium concentrations (0.01 M, 0.03 M, 0.05 M, 0.07 M and 0.09 M) have been synthesized by sol gel method. The X-ray diffraction (XRD) patterns show that the CdO and Ga-doped CdO films exhibit cubic structure. The chemical composition of the Ga-doped CdO films was studied using X-ray photoelectron spectroscopy (XPS). XPS results clearly showed the existence of Ga as a doping element in the CdO crystal lattice. Optical absorption spectra of Ga-doped CdO films shows that absorption edge is slightly shifted toward longer wavelength side (red shift) when compared to that of CdO. The optical band gap of CdO film was found to decrease with increasing Ga-doping concentration. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:559 / 563
页数:5
相关论文
共 22 条
[11]   Effect of indium doping in CdO thin films prepared by spray pyrolysis technique [J].
Kumaravel, R. ;
Ramamurthi, K. ;
Krishnakumar, V. .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2010, 71 (11) :1545-1549
[12]   A temperature dependant crystal orientation transition of cadmium oxide films deposited by metal organic chemical vapour deposition [J].
Lamb, D. A. ;
Irvine, S. J. C. .
JOURNAL OF CRYSTAL GROWTH, 2011, 332 (01) :17-20
[13]   Effect of annealing temperature on structural, electrical and optical properties of spray pyrolytic nanocrystalline CdO thin films [J].
Rahman, M. Azizar ;
Khan, M. K. R. .
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2014, 24 :26-33
[14]   Bandgap widening in highly conducting CdO thin film by Ti incorporation through radio frequency magnetron sputtering technique [J].
Saha, B. ;
Thapa, R. ;
Chattopadhyay, K. K. .
SOLID STATE COMMUNICATIONS, 2008, 145 (1-2) :33-37
[15]   Electrical and optical properties of Al doped cadmium oxide thin films deposited by radio frequency magnetron sputtering [J].
Saha, B. ;
Das, S. ;
Chattopadhyay, K. K. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2007, 91 (18) :1692-1697
[16]   Structural and optical properties of Ba-doped CdO films prepared by SILAR method [J].
Sahin, B. ;
Gulen, Y. ;
Bayansal, F. ;
Cetinkara, H. A. ;
Guder, H. S. .
SUPERLATTICES AND MICROSTRUCTURES, 2014, 65 :56-63
[17]   Dependence of electrical and optical properties of sol-gel prepared undoped cadmium oxide thin films on annealing temperature [J].
Santos-Cruz, J ;
Torres-Delgado, G ;
Castanedo-Perez, R ;
Jiménez-Sandoval, S ;
Jiménez-Sandoval, O ;
Zúñiga-Romero, CI ;
Marín, JM ;
Zelaya-Angel, O .
THIN SOLID FILMS, 2005, 493 (1-2) :83-87
[18]   Enhanced photovoltaic performance of inverted organic solar cells with In-doped ZnO as an electron extraction layer [J].
Thambidurai, M. ;
Kim, Jun Young ;
Kang, Chan-mo ;
Muthukumarasamy, N. ;
Song, Hyung-Jun ;
Song, Jiyun ;
Ko, Youngjun ;
Velauthapillai, Dhayalan ;
Lee, Changhee .
RENEWABLE ENERGY, 2014, 66 :433-442
[19]   Optical properties of Al-CdO nano-clusters thin films [J].
Yahia, I. S. ;
Salem, G. F. ;
Abd El-sadek, M. S. ;
Yakuphanoglu, F. .
SUPERLATTICES AND MICROSTRUCTURES, 2013, 64 :178-184
[20]   Synthesis and electro-optic properties of nanosized-boron doped cadmium oxide thin films for solar cell applications [J].
Yakuphanoglu, F. .
SOLAR ENERGY, 2011, 85 (11) :2704-2709