An alternating low band-gap polyfluorene for optoelectronic devices

被引：110

作者：

Perzon, Erik ^{[1
]}

Wang, Xiangjun

Admassie, Shielis

Inganas, Olle

Andersson, Mats R.

机构：

[1] Chalmers Univ Technol, Dept Biol & Chem Engn, SE-41296 Gothenburg, Sweden

[2] Linkoping Univ, SE-58183 Linkoping, Sweden

来源：

POLYMER | 2006年 / 47卷 / 12期

关键词：

conjugated polymers; polymer synthesis; plastic solar cells;

D O I：

10.1016/j.polymer.2006.03.110

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

An alternating polyfluorene (APFO) with low band-gap segments named APFO-Green1 has been designed and synthesized for use in optoelectronic devices. The low band-gap segment consists of an electron acceptor (A), fenced by electron donors (D). This D-A-D configuration leads to a partial charge transfer in the polymer backbone, and thereby a low band-gap (1.3 eV). Results obtained from characterization of APFO-Green1 include light absorption and emission at extended wavelengths as well as high hole mobility. Furthermore, blends of the polymer with different fullerene derivatives exhibit unusually high photovoltaic performance at long wavelengths, making this type of conjugated polymers promising for plastic solar cell applications. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：4261 / 4268

页数：8

共 53 条

[1] Substituted polythiophenes designed for optoelectronic devices and conductors [J].

Andersson, MR ;

Thomas, O ;

Mammo, W ;

Svensson, M ;

Theander, M ;

Inganäs, O .

JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (09) :1933-1940

[2] High-performance plastic transistors fabricated by printing techniques [J].

Bao, ZN ;

Feng, Y ;

Dodabalapur, A ;

Raju, VR ;

Lovinger, AJ .

CHEMISTRY OF MATERIALS, 1997, 9 (06) :1299-&

[3] THERMAL CONTROL OF NEAR-INFRARED AND VISIBLE ELECTROLUMINESCENCE IN ALKYL-PHENYL SUBSTITUTED POLYTHIOPHENES [J].

BERGGREN, M ;

GUSTAFSSON, G ;

INGANAS, O ;

ANDERSSON, MR ;

WENNERSTROM, O ;

HJERTBERG, T .

APPLIED PHYSICS LETTERS, 1994, 65 (12) :1489-1491

[4]

Bernius MT, 2000, ADV MATER, V12, P1737, DOI 10.1002/1521-4095(200012)12:23<1737::AID-ADMA1737>3.0.CO

[5]

2-N

[6] The influence of materials work function on the open circuit voltage of plastic solar cells [J].

Brabec, CJ ;

Cravino, A ;

Meissner, D ;

Sariciftci, NS ;

Rispens, MT ;

Sanchez, L ;

Hummelen, JC ;

Fromherz, T .

THIN SOLID FILMS, 2002, 403 :368-372

[7] Organic photovoltaics: technology and market [J].

Brabec, CJ .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2004, 83 (2-3) :273-292

[8] CHAIN-LENGTH DEPENDENCE OF ELECTRONIC AND ELECTROCHEMICAL PROPERTIES OF CONJUGATED SYSTEMS - POLYACETYLENE, POLYPHENYLENE, POLYTHIOPHENE, AND POLYPYRROLE [J].

BREDAS, JL ;

SILBEY, R ;

BOUDREAUX, DS ;

CHANCE, RR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (22) :6555-6559

[9] LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS [J].

BURROUGHES, JH ;

BRADLEY, DDC ;

BROWN, AR ;

MARKS, RN ;

MACKAY, K ;

FRIEND, RH ;

BURN, PL ;

HOLMES, AB .

NATURE, 1990, 347 (6293) :539-541

[10] Extended photocurrent spectrum of a low band gap polymer in a bulk heterojunction solar cell [J].

Campos, LM ;

Tontcheva, A ;

Günes, S ;

Sonmez, G ;

Neugebauer, H ;

Sariciftci, NS ;

Wudl, F .

CHEMISTRY OF MATERIALS, 2005, 17 (16) :4031-4033

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