Synthetic, structural, and biochemical studies of organotin(IV) with Schiff bases having nitrogen and sulphur donor ligands

被引：67

作者：

Singh, Har Lal ^{[1
]}

Varshney, A. K.

机构：

[1] Shekhwatai Engn Coll, Dept Chem, Dundlod 333702, Rajasthan, India

[2] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India

来源：

BIOINORGANIC CHEMISTRY AND APPLICATIONS | 2006年 / 2006卷

关键词：

D O I：

10.1155/BCA/2006/23245

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Three bidentate Schiff bases having nitrogen and sulphur donor sequences were prepared by condensing S-benzyldithiocarbazate (NH2NHCS2CH2C6H5) with heterocyclic aldehydes. The reaction of diphenyltin dichloride with Schiff bases leads to the formation of a new series of organotin(IV) complexes. An attempt has been made to prove their structures on the basis of elemental analyses, conductance measurements, molecular weights determinations, UV, infrared, and multinuclear magnetic resonance (H-1, C-13, and Sn-119) spectral studies. Organotin(IV) complexes were five- and six-coordinate. Schiff bases and their corresponding organotin complexes have also been screened for their antibacterial and antifungal activities and found to be quite active in this respect.

引用

页码：1 / 7

页数：7

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