α,α-Dicyanoalkenes: versatile vinylogous nucleophiles for organic synthesis

被引：122
作者：
Cui, Hai-Lei [1 ]
Chen, Ying-Chun [1 ,2 ]
机构：
[1] Sichuan Univ, W China Sch Pharm, Key Lab Drug Targeting & Drug Delivery Syst, Dept Med Chem,Educ Minist, Chengdu 610041, Peoples R China
[2] Sichuan Univ, W China Hosp, State Key Lab Biotherapy, Chengdu 610041, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 30期
基金：
芬兰科学院;
关键词：
BAYLIS-HILLMAN ACETATES; ASYMMETRIC MICHAEL ADDITION; MODIFIED CINCHONA ALKALOIDS; RUTHENIUM AMIDO COMPLEXES; CARBON BOND FORMATION; MANNICH REACTION; ALLYLIC ALKYLATION; ALPHA; BETA-UNSATURATED ALDEHYDES; TRIFLUOROMETHYLATING AGENTS; TRANSFER HYDROGENATION;
D O I：
10.1039/b906201g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
alpha,alpha-Dicyanoalkenes are electron-deficient alkenes and inherently behave as electrophiles. Over the past five years some significant progress has been achieved by using alpha,alpha-dicyanoalkenes as vinylogous donors in C-C bond forming and other functionalisation reactions, especially for the construction of multifunctional products. In this feature article we will present the successful development of vinylogous reactions of alpha,alpha-dicyanoalkenes by our group and other groups.
引用
收藏
页码：4479 / 4486
页数：8
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