Volumetric and acoustic properties of the ternary mixture 1-butanol+1-chlorobutane plus tetrahydrofuran at 283.15, 298.15, and 313.15 K

被引:13
作者
Valén, A
Gascón, I
Lafuente, C
Urieta, JS
Royo, FM [1 ]
Postigo, M
机构
[1] Univ Zaragoza, Dept Quim Organ Quim Fis, Fac Ciencias, E-50009 Zaragoza, Spain
[2] UN Comahue, Fac Ingn, Dept Quim, Catedra Fisicoquim, RA-1400 Buenos Aires, DF, Argentina
关键词
1-butanol; 1-chlorobutane; density; excess molar volumes; isentropic compressibilities; speeds of sound; ternary mixture; tetrahydrofuran;
D O I
10.1023/A:1020892201382
中图分类号
O414.1 [热力学];
学科分类号
摘要
Experimental densities (rho) and speeds of sound (u) were obtained for the ternary system (1-butanol + 1-chlorobutane + tetrahydrofuran) at three temperatures: 283.15, 298.15, and 313.15 K. Excess molar volumes (V-E) and isentropic compressibility deviations (Deltak(S)) have been calculated from experimental data. A discussion of the thermodynamic behavior of the ternary system with temperature variation is presented.
引用
收藏
页码:1587 / 1598
页数:12
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