Thioureas: new ligands for the metal catalyzed asymmetric reduction of carbonyl compounds

被引：50
作者：
Touchard, F
Fache, F
Lemaire, M
机构：
[1] UNIV LYON 1,CPE,INST RECH CATALYSE,F-69622 VILLEURBANNE,FRANCE
[2] UNIV LYON 1,CPE,CNRS,LAB CATALYSE & SYNTH ORGAN,F-69622 VILLEURBANNE,FRANCE
来源：
TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 19期
关键词：
D O I：
10.1016/S0957-4166(97)00396-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The catalytic enantioselective hydride transfer reduction of prochiral ketones using differently substituted mono and dithioureas with several catalyst precursors is reported. The best results are obtained with a ruthenium complex and a C-2 symmetric ligand. (C) 1997 Elsevier Science Ltd.
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页码：3319 / 3326
页数：8
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