Interfacial transport in lithium-ion conductors

被引：10

作者：

Wang, Shaofei ^{[1
]}

Chen, Liquan ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China

来源：

CHINESE PHYSICS B | 2016年 / 25卷 / 01期

基金：

中国国家自然科学基金;

关键词：

ionic conductivity; diffusion; interface; grain boundary; lithium battery; impedance; nuclear magnetic resonance; POLYMER ELECTROLYTES; LI-ION; CERAMIC ELECTROLYTE; DIFFUSION; NANOCRYSTALLINE; CONDUCTIVITY; IMPEDANCE; POLARIZATION; RELAXATION; NMR;

D O I：

10.1088/1674-1056/25/1/018202

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Physical models of ion diffusion at different interfaces are reviewed. The use of impedance spectroscopy (IS), nuclear magnetic resonance (NMR), and secondary ion mass spectrometry (SIMS) techniques are also discussed. The diffusion of ions is fundamental to the operation of lithium-ion batteries, taking place not only within the grains but also across different interfaces. Interfacial ion transport usually contributes to the majority of the resistance in lithium-ion batteries. A greater understanding of the interfacial diffusion of ions is crucial to improving battery performance.

引用

页数：8

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