Mono- and Dinuclear Macrocyclic Calcium Complexes as Platforms for Mixed-Metal Complexes and Clusters

被引：12

作者：

Connolly, Emma A. ^{[1
]}

Leeland, James W. ^{[1
]}

Love, Jason B. ^{[1
]}

机构：

[1] Univ Edinburgh, EaStCHEM Sch Chem, Joseph Black Bldg,David Brewster Rd, Edinburgh EH9 3FJ, Midlothian, Scotland

来源：

INORGANIC CHEMISTRY | 2016年 / 55卷 / 02期

基金：

英国工程与自然科学研究理事会;

关键词：

RING-OPENING POLYMERIZATION; STRUCTURAL-CHARACTERIZATION; CYCLIC MONOMERS; POLY(LACTIDE); HYDRIDE; LIGANDS; ALKALI;

D O I：

10.1021/acs.inorgchem.5b02289

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mono- and dinuclear calcium complexes of the Schiff-base macrocycles H4L have been prepared and characterized spectroscopically and crystallographically. In the formation of Ca(THF)(2)(H2L1), Ca-2(THF)(2)(mu-THF)(L-1), and Ca-2(THF)(4)(L-2), the ligand framework adopts a bowl-shaped conformation instead of the conventional wedge, Pacman-shaped structure as seen with the anthracenyl-hinged complex Ca-2(py)(5)(L-3). The mononuclear calcium complex Ca(THF)(2)(H2L1) reacts with various equivalents of LiN(SiMe3)(2) to form calcium/alkali metal clusters and dinuclear transition metal complexes when reacted subsequently with transition metal salts. The dinuclear calcium complex Ca-2(THF)(2)(mu- THF)(L-1), when reacted with various equivalents of NaOH, is shown to act as a platform for the formation of calcium/alkali metal hydroxide clusters, displaying alternate wedged and bowl-shaped conformations.

引用

页码：840 / 847

页数：8

共 42 条

[31] The Effects of Redox-Inactive Metal Ions on the Activation of Dioxygen: Isolation and Characterization of a Heterobimetallic Complex Containing a MnIII-(μ-OH)-CaII Core [J].