Magneto-structural properties of Ni-Zn nanoferrites synthesized by the low-temperature auto-combustion method

被引：30
作者：
Ehi-Eromosele, C. O. [1 ]
Ita, B. I. [1 ,2 ]
Iweala, E. E.J [3 ]
Adalikwu, S. A. [2 ]
Anawe, P. A. L. [4 ]
机构：
[1] Covenant Univ, Dept Chem, Ota, Nigeria
[2] Univ Calabar, Dept Pure & Appl Chem, Calabar, Nigeria
[3] Covenant Univ, Dept Biol Sci, Ota, Nigeria
[4] Covenant Univ, Dept Petr Engn, Ota, Nigeria
来源：
BULLETIN OF MATERIALS SCIENCE | 2015年 / 38卷 / 05期
关键词：
Ni-Zn ferrites; fuel-rich composition; combustion synthesis; Raman studies; magnetism; NICKEL-ZINC FERRITES; CITRATE PRECURSOR METHOD; MAGNETIC-PROPERTIES; NIFE2O4; NANOPARTICLES; ANNEALING TEMPERATURE; STRUCTURAL-PROPERTIES; MFE2O4; M; NI1-XZNXFE2O4; SUBSTITUTION; MN;
D O I：
10.1007/s12034-015-1038-1
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Using nickel, zinc and ferric nitrates, and glycine in a fuel-rich composition, Ni1-x,ZnxFe2O4 nanoparticles were prepared by a simple low-temperature auto-combustion method without further sintering at high temperatures. The auto-combusted powders obtained were characterized by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy, energy-dispersive X-ray (EDAX) analysis and vibrating scanning magnetometer measurements. XRD confirms the formation of pure nanocrystalline spinel phases with an average diameter of about 55 nm. Raman spectra show tetrahedral and octahedral sites in the structure of Ni1-x,ZnxFe2O4 and also imply the doping of Zn2+ and displacement of Fe3+ ions from the tetrahedral site. EDAX showed that the samples were close to the nominal compositions. The magnetic measurement shows that the saturation magnetization and remanence magnetization decreases with the increase in the zinc content.
引用
收藏
页码：1465 / 1472
页数：8
相关论文
共 39 条
[1]   Raman study of NiFe2O4 nanoparticles, bulk and films: effect of laser power [J].
Ahlawat, Anju ;
Sathe, V. G. .
JOURNAL OF RAMAN SPECTROSCOPY, 2011, 42 (05) :1087-1094
[2]   Influence of zinc substitution on structural and electrical properties of Ni1-xZnxFe2O4 ferrites [J].
Ajmal, Muhammad ;
Maqsood, Aschari .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2007, 139 (2-3) :164-170
[3]   Localized canting effect in Zn-substituted Ni ferrites [J].
Bercoff, PG ;
Bertorello, HR .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2000, 213 (1-2) :56-62
[4]   The continuous hydrothermal synthesis of nano-particulate ferrites in near critical and supercritical water [J].
Cabañas, A ;
Poliakoff, M .
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (05) :1408-1416
[5]   A Structural and Magnetic Investigation of the Inversion Degree in Ferrite Nanocrystals MFe2O4 (M = Mn, Co, Ni) [J].
Carta, D. ;
Casula, M. F. ;
Falqui, A. ;
Loche, D. ;
Mountjoy, G. ;
Sangregorio, C. ;
Corrias, A. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (20) :8606-8615
[6]   Magnetic and structural properties of NiFe2O4 ferrite nanopowder doped with Zn2+ [J].
Costa, A. C. F. M. ;
Silva, V. J. ;
Cornejo, D. R. ;
Morelli, M. R. ;
Kiminami, R. H. G. A. ;
Gama, L. .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2008, 320 (14) :E370-E372
[7]   Influence of calcination temperature on the morphology and magnetic properties of Ni-Zn ferrite applied as an electromagnetic energy absorber [J].
Costa, A. C. F. M. ;
Diniz, A. P. ;
Silva, V. J. ;
Kiminami, R. H. G. A. ;
Cornejo, D. R. ;
Gama, A. M. ;
Rezende, M. C. ;
Gama, L. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 483 (1-2) :563-565
[8]  
COSTA ACF, 2002, THESIS FEDERAL U SAO
[9]   Effect of heating conditions during combustion synthesis on the characteristics of Ni0.5Zn0.5Fe2O4 nanopowders [J].
Costa, ACFM ;
Tortella, E ;
Morelli, MR ;
Kaufman, M ;
Kiminami, RHGA .
JOURNAL OF MATERIALS SCIENCE, 2002, 37 (17) :3569-3572
[10]   Synthesis, microstructure and magnetic properties of Ni-Zn ferrites [J].
Costa, ACFM ;
Tortella, E ;
Morelli, MR ;
Kiminami, RHGA .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2003, 256 (1-3) :174-182
1234