Heat capacity of NaNO2

被引:12
作者
Kourkova, L. [1 ]
Svoboda, R. [2 ]
Sadovska, G. [1 ]
Podzemna, V. [1 ]
Kohutova, A. [1 ]
机构
[1] Univ Pardubice, Dept Inorgan Technol, Fac Chem Technol, Pardubice, Czech Republic
[2] Univ Pardubice, Dept Phys Chem, Fac Chem Technol, Pardubice, Czech Republic
关键词
Sodium nitrite; Heat capacity; Enthalpy; Phase change materials; Calorimetry; DIFFERENTIAL SCANNING CALORIMETRY; PHASE-TRANSITIONS; SODIUM-NITRITE; X-RAY; ENTHALPY; CRYSTAL;
D O I
10.1016/j.tca.2009.03.005
中图分类号
O414.1 [热力学];
学科分类号
摘要
Heat capacity in solid state was for the sodium nitrite (NaNO(2)) measured by using two types of calorimeters. The measurements were performed in the temperature range 273.15-583.15 K. Three phase changes were observed in this temperature range - one melting and two transitions between different structural modifications. Concerning the transitions between structural modifications, the first was observed at 437.2 +/- 0.1 K and the second was found at 438.7 +/- 0.1 K. Temperature of melting was then determined to be 553.2 +/- 0.2 K with the corresponding heat of fusion being equal to 13.9 +/- 0.1 kJ mol(-1). (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:80 / 83
页数:4
相关论文
共 24 条
[1]   The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].
Allen, FH .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388
[2]   STUDY OF COMMENSURATE AND INCOMMENSURATE PHASES IN NANO2 BY NA-23 NMR [J].
BUCHHEIT, W ;
HERTH, G ;
PETERSSON, J .
SOLID STATE COMMUNICATIONS, 1981, 40 (04) :411-414
[3]  
CASES JC, 1973, REV CHIM MINER, V10, P577
[4]   Thermal energy storage and phase change materials: An overview [J].
Demirbas, M. Fatih .
ENERGY SOURCES PART B-ECONOMICS PLANNING AND POLICY, 2006, 1 (01) :85-95
[5]   DIELECTRIC STUDY OF RELAXATION PROCESS IN THE INCOMMENSURATE PHASE OF SODIUM-NITRITE [J].
EMA, K ;
HAMANO, K ;
MARUYAMA, H .
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1988, 57 (06) :2174-2181
[6]   A detailed IR study of the order-disorder phase transition of NaNO2 [J].
Fahim, MA .
THERMOCHIMICA ACTA, 2000, 363 (1-2) :121-127
[7]   Ferroelectric phase transitions in sodium nitrite nanocomposites [J].
Fokin, A. ;
Kumzerov, Yu. ;
Koroleva, E. ;
Naberezhnov, A. ;
Smirnov, O. ;
Tovar, M. ;
Vakhrushev, S. ;
Glazman, M. .
JOURNAL OF ELECTROCERAMICS, 2009, 22 (1-3) :270-275
[9]   SPECIFIC-HEAT OF NANO2 NEAR ITS TRANSITION POINTS [J].
HATTA, I ;
IKUSHIMA, A .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1973, 34 (01) :57-66
[10]   Application of dynamic differential scanning calorimetry to study of phase transitions [J].
Hatta, I ;
Ichikawa, H ;
Todoki, M .
THERMOCHIMICA ACTA, 1995, 267 :83-94