The Local Structure and Hydration Processes of Halogen-Substituted Perovskites Based on Ba4In2Zr2O11

被引：1

作者：

Tarasova, N. A. ^{[1
]}

Galisheva, A. O. ^{[1
]}

Animitsa, I. E. ^{[1
]}

机构：

[1] Ural Fed Univ, Inst Nat Sci & Math, Ekaterinburg 620026, Russia

来源：

OPTICS AND SPECTROSCOPY | 2019年 / 126卷 / 04期

基金：

俄罗斯科学基金会;

关键词：

FERROELASTIC PHASE-TRANSITIONS; SHORT-RANGE STRUCTURE; ELECTRIC PROPERTIES; ABSORPTION; OXYFLUORIDES; INSERTION;

D O I：

10.1134/S0030400X19040222

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Halogen-substituted perovskites Ba4In2Zr2O10.95F0.1 and Ba4In2Zr2O10.95Cl0.1 are synthesized, and their single-phase composition is verified by X-ray diffraction analysis. Their ability of the studied phases to hydrate and form energetically unequal OH- groups is proved. It is found that introduction of halide ions leads to a decrease in the hydration degree with respect to the matrix composition, which is explained by a decrease in the crystal unit cell free volume Processes.

引用

页码：336 / 340

页数：5

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