Diels-Alder reaction with cyclopentadiene and electronic structures of (η5-cyclopentadienyl)M(CO)x(η1-N-maleimidato) (M = Fe, Mo, W, x=2 or 3)

被引：6

作者：

Rudolf, Bogna ^{[1
]}

Palusiak, Marcin ^{[2
]}

Zakrzewski, Janusz ^{[1
]}

机构：

[1] Univ Lodz, Dept Organ Chem, PL-90136 Lodz, Poland

[2] Univ Lodz, Dept Crystallog & Crystal Chem, PL-90236 Lodz, Poland

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2009年 / 694卷 / 9-10期

关键词：

Maleimidato complexes; Cyclopentadiene; Diels-Alder reaction; X-ray structure; DFT calculations; EFFECTIVE CORE POTENTIALS; MOLECULAR CALCULATIONS; CRYSTAL-STRUCTURE; COMPLEXES; PROTEIN; BIOMOLECULES; ATOMS;

D O I：

10.1016/j.jorganchem.2008.12.031

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Diels-Alder reaction of (eta(5)-cyclopentadienyl)M(CO)(x)(eta(1)-N-maleimidato) complexes (M = Fe, Mo, W, x = 2 or 3) with cyclopentadiene has been studied. The observed order of reactivity was: N-ethylmaleimide > W complex > Mo complex > Fe complex. The X-ray structures of the adducts have been determined for M = W and Fe. DFT calculations on the starting complexes have been performed to explain the observed reactivity order. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：1354 / 1358

页数：5

共 30 条

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