Application of H-1-NOESY NMR spectroscopy to the investigation of ion pair solution structures of organometallic complexes by the detection of interionic contacts

被引：56

作者：

Bellachioma, G ^{[1
]}

Cardaci, G ^{[1
]}

Macchioni, A ^{[1
]}

Reichenbach, G ^{[1
]}

Terenzi, S ^{[1
]}

机构：

[1] UNIV PERUGIA,DIPARTIMENTO CHIM,I-06100 PERUGIA,ITALY

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 21期

关键词：

D O I：

10.1021/om9605645

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The interionic solution structures of trans-[Ru(PMe(3))(2)(CO)(COMe)(pz(2)-CH2)]BPh(4) and trans -[Ru-(PMe(3))(2)(CO)(COMe)(eta(2)-pz(3)-CH)]BPh(4) have been ''directly'' investigated by the detection of interionic contacts in H-1-NOESY NMR spectra between the protons of the organometallic fragments and those of the counterion. BPh(4)(-). A comparison with the solid-state structures obtained by single-crystal X-ray studies has been made.

引用

页码：4349 / 4351

页数：3

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