Syntheses and redox behavior of novel cyclic hosts having multiple redox centers of NAD(+) analogue

被引：12

作者：

Kuroda, Y ^{[1
]}

Seshimo, H ^{[1
]}

Kondo, T ^{[1
]}

Shiba, M ^{[1
]}

Ogoshi, H ^{[1
]}

机构：

[1] KYOTO UNIV,DEPT SYNTHET CHEM & BIOL CHEM,SAKYO KU,KYOTO 60601,JAPAN

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 22期

关键词：

D O I：

10.1016/S0040-4039(97)00784-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new series of cyclophanes having 3,5-dicarbamoylpyridinium moieties were synthesized by the stepwise reactions starting from half protected compounds. The one-electron reduction potentials of these new cyclophane type NAD(+) analogues are determined by the cyclic voltammetric method. The results indicate that the reduction potentials are primarily regulated by the through-bond mechanism. (C) 1997 Elsevier Science Ltd.

引用

页码：3939 / 3942

页数：4

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