Electrical conductivity and electroluminescence of a new anthracene-based metal-organic framework with π-conjugated zigzag chains

被引：102

作者：

Chen, Dashu ^{[1
]}

Xing, Hongzhu ^{[1
]}

Su, Zhongmin ^{[1
]}

Wang, Chungang ^{[1
]}

机构：

[1] NE Normal Univ, Coll Chem, Prov Key Lab Adv Energy Mat, Changchun 130024, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 10期

基金：

中国国家自然科学基金;

关键词：

LIGHT-EMITTING-DIODES; CHARGE MOBILITY; BLUE; DEVICES; DERIVATIVES; CRYSTALS;

D O I：

10.1039/c5cc09065b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new three-dimensional microporous MOF has been constructed using a highly conjugated anthracene-based ligand. The rarely occurring long-range pi-stacking of the ligand in the form of a zigzag chain has been found in the MOF structure, which provides not only a new charge transport pathway with high electrical conductivity of 1.3 (+/- 0.5) x 10(-3) S cm(-1) but also an electroluminescence property with an emission centred at 575 nm.

引用

页码：2019 / 2022

页数：4

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