Allylic Arylation of 1,3-Dienes via Hydroboration/Migrative Suzuki-Miyaura Cross-Coupling Reactions

被引：20

作者：

Zhang, Xiao-Ming ^{[1
,2
]}

Yang, Jie ^{[1
,2
]}

Zhuang, Qing-Bo ^{[1
,2
]}

Tu, Yong-Qiang ^{[1
,2
,3
]}

Chen, Zongyuan ^{[4
]}

Shao, Hui ^{[3
]}

Wang, Shao-Hua ^{[1
,2
,5
]}

Zhang, Fu-Min ^{[1
,2
]}

机构：

[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

[2] Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China

[3] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China

[4] Lanzhou Univ, Sch Nucl Sci & Technol, Radiochem Lab, Lanzhou 730000, Peoples R China

[5] Lanzhou Univ, Sch Pharm, Lanzhou 730000, Peoples R China

来源：

ACS CATALYSIS | 2018年 / 8卷 / 07期

关键词：

palladium catalysis; Suzuki-Miyaura reaction; migrative cross-coupling; allylic compounds; regioselectivity; ALKENE ISOMERIZATION-HYDROBORATION; CATALYZED BETA-ARYLATION; TERTIARY BORONIC ESTERS; CARBON BOND FORMATION; ORGANIC-SYNTHESIS; TERMINAL ALKENES; REMOTE FUNCTIONALIZATION; CONJUGATED DIENES; COBALT CATALYSTS; ARYL HALIDES;

D O I：

10.1021/acscatal.8b01823

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydroboration/Pd-catalyzed migrative Suzuki-Miyaura cross-coupling of 1,3-dienes with electron deficient aryl halides has been developed, which enables the synthesis of branched allylarenes directly from primary homoallylic alkyl boranes. A ligand-tuned linear- or branch-selective coupling for these aryl halides has also been achieved.

引用

页码：6094 / 6099

页数：11

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