Efficient and persistent cold cathode emission from CuPc nanotubes: a joint experimental and simulation investigation

被引:27
作者
Ghorai, Uttam Kumar [1 ]
Das, Swati [2 ]
Saha, Subhajit [1 ]
Mazumder, Nilesh [2 ]
Sen, Dipayan
Chattopadhyay, Kalyan Kumar [1 ,2 ]
机构
[1] Jadavpur Univ, Sch Mat Sci & Nanotechnol, Kolkata 700032, India
[2] Jadavpur Univ, Dept Phys, Thin Film & Nanosci Lab, Kolkata 700032, India
关键词
FIELD-EMISSION; COPPER PHTHALOCYANINE; ELECTRON-EMISSION; THIN-FILMS; NANOSTRUCTURES; NANOWIRES; ARRAYS; TEMPERATURE; NANORIBBONS; FABRICATION;
D O I
10.1039/c4dt00300d
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In the current report, chemically synthesized copper phthalocyanine (CuPc) nanotubes are shown to exhibit unprecedentedly well cold cathode emission characteristics with turn-on field (3.2 V mu m(-1)) and stable emission during long intervals (200 min). Simulation of electric field distribution via finite element method around an isolated nanotube emitter in a manner parallel to the experimental setup (inter-electrode distance = 180 mu m) exhibits good corroboration of theoretical premises with experimental findings. Obtained results strongly indicate CuPc nanotubes to be potential candidate as cold cathode emitter for electron emission based applications such as field emission displays and vacuum nano-electronic devices.
引用
收藏
页码:9260 / 9266
页数:7
相关论文
共 46 条
[1]   Low-macroscopic field emission properties of wide bandgap copper aluminium oxide nanoparticles for low-power panel applications [J].
Banerjee, Arghya Narayan ;
Joo, Sang W. .
NANOTECHNOLOGY, 2011, 22 (36)
[2]   Comparative Gas Sensing in Cobalt, Nickel, Copper, Zinc, and Metal-Free Phthalocyanine Chemiresistors [J].
Bohrer, Forest I. ;
Colesniuc, Corneliu N. ;
Park, Jeongwon ;
Ruidiaz, Manuel E. ;
Schuller, Ivan K. ;
Kummel, Andrew C. ;
Trogler, William C. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (02) :478-485
[3]   Introducing organic nanowire transistors [J].
Briseno, Alejandro L. ;
Mannsfeld, Stefan C. B. ;
Jenekhe, Samson A. ;
Bao, Zhenan ;
Xia, Younan .
MATERIALS TODAY, 2008, 11 (04) :38-47
[4]   Field Emission Properties of ZnO Single Crystal Microtubes [J].
Cheng, Jiping ;
Zhang, Yunjin ;
Guo, Ruyan .
JOURNAL OF APPLIED PHYSICS, 2009, 105 (03)
[5]   Reduced Graphene Oxide/Copper Phthalocyanine Composite and Its Optoelectrical Properties [J].
Chunder, Anindarupa ;
Pal, Tanusri ;
Khondaker, Saiful I. ;
Zhai, Lei .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (35) :15129-15135
[6]   Fabrication and field-emission properties of large-area nanostructures of the organic charge-transfer complex Cu-TCNAQ [J].
Cui, Shuang ;
Li, Yuliang ;
Guo, Yanbing ;
Liu, Huibiao ;
Song, Yinglin ;
Xu, Jialiang ;
Lv, Jing ;
Zhu, Mei ;
Zhu, Daoben .
ADVANCED MATERIALS, 2008, 20 (02) :309-+
[7]   Effects of substrate temperature on copper(II) phthalocyanine thin films [J].
E, JY ;
Kim, S ;
Lim, EJ ;
Lee, KJ ;
Cha, DJ ;
Friedman, B .
APPLIED SURFACE SCIENCE, 2003, 205 (1-4) :274-279
[8]   Electron emission in intense electric fields [J].
Fowler, RH ;
Nordheim, L .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-CONTAINING PAPERS OF A MATHEMATICAL AND PHYSICAL CHARACTER, 1928, 119 (781) :173-181
[9]   Facile Synthesis, Self-assembly Mechanism and Field Emission Property of Copper Phthalocyanine Nanowires [J].
Ghorai, U. K. ;
Saha, S. ;
Shee, S. ;
Chattopadhyay, K. K. .
PROCEEDING OF INTERNATIONAL CONFERENCE ON RECENT TRENDS IN APPLIED PHYSICS & MATERIAL SCIENCE (RAM 2013), 2013, 1536 :223-224
[10]   Zinc phthalocyanine hierarchical nanostructure with hollow interior space: Solvent-thermal synthesis and high visible photocatalytic property [J].
Guo, Zengcai ;
Chen, Bin ;
Zhang, Mingyi ;
Mu, Jingbo ;
Shao, Changlu ;
Liu, Yichun .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2010, 348 (01) :37-42