First examples of organosilica-based ionogels: synthesis and electrochemical behavior

被引：13

作者：

Taubert, Andreas ^{[1
]}

Loebbicke, Ruben ^{[1
]}

Kirchner, Barbara ^{[2
]}

Leroux, Fabrice ^{[3
]}

机构：

[1] Univ Potsdam, Inst Chem, D-14476 Potsdam, Germany

[2] Univ Bonn, Mulliken Ctr Theoret Chem, Inst Phys & Theoret Chem, Beringstrasse 4 6, D-53115 Bonn, Germany

[3] Univ Blaise Pascal, Inst Chim Clermont Ferrand ICCF UMR 6296, Inorgan Mat, Chim 5, Campus Cezeaux,24 Ave Landais,BP 80026 63171 Aubi, F-63171 Aubiere, France

来源：

BEILSTEIN JOURNAL OF NANOTECHNOLOGY | 2017年 / 8卷

关键词：

ionic liquids; ionogels; organosilica; proton conductivity; SHORT-RANGE ORDER; IONIC-LIQUID; SILICA; MEMBRANES; DYNAMICS; ELECTROLYTES; PERFORMANCES; ENERGY;

D O I：

10.3762/bjnano.8.77

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The article describes the synthesis and properties of new ionogels for ion transport. A new preparation process using an organic linker, bis(3-(trimethoxysilyl) propyl) amine (BTMSPA), yields stable organosilica matrix materials. The second ionogel component, the ionic liquid 1-methyl-3-(4-sulfobutyl) imidazolium 4-methylbenzenesulfonate, [BmimSO(3)H][PTS], can easily be prepared with near-quantitative yields. [BmimSO(3)H][PTS] is the proton conducting species in the ionogel. By combining the stable organosilica matrix with the sulfonated ionic liquid, mechanically stable, and highly conductive ionogels with application potential in sensors or fuel cells can be prepared.

引用

收藏

页码：736 / 751

页数：16

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