Synthesis, characterization, and crystal structure of a 3D coordination polymer [Cd2•(H3C9N12)•Cl•(H2O)2]

被引：1

作者：

Tian, Hui ^{[1
,2
]}

Wu, Yi-Chen ^{[1
,2
]}

Zhang, Shi-Yang ^{[1
,2
]}

Dong, Bao-Xia ^{[1
,2
]}

Liu, Chun-Bo ^{[1
]}

Liu, Wen-Long ^{[2
]}

Teng, Yun-Lei ^{[2
]}

机构：

[1] Yangzhou Univ, Jiangsu Key Lab Environm Mat & Environm Engn, Yangzhou, Jiangsu, Peoples R China

[2] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China

来源：

INORGANIC AND NANO-METAL CHEMISTRY | 2017年 / 47卷 / 04期

关键词：

Coordination polymer; crystal structure; tetrazole; METAL-ORGANIC FRAMEWORK; HYDROGEN STORAGE; CO2; CAPTURE; SITES;

D O I：

10.1080/15533174.2016.1186093

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new Cd(II) coordination polymer has been prepared by solvothermal synthesis and characterized by single-crystal X-ray diffraction, IR, and element analysis. Complex [Cd-2 center dot BTT center dot Cl center dot(H2O)(2)](n) (1) [H3BTT = 1,3,5-tris(2H-tetrazol-5-yl) benzene] is monoclinic, space group P2(1)7sol;c with a = 10.601(11) angstrom b = 15.5428(16) angstrom, c = 9.0083(9) angstrom, beta = 106.117(3)degrees, V = 1426.0(3) A(3). The final refinment gave R = 0.0192, and wR = 0.0473 for reflections with I > 2 sigma(I). Single-crystal X-ray diffraction analysis reveals that the compound 1 is a novel three-dimensional framework, featuring three types of connections of the tetrazole ring.

引用

页码：549 / 552

页数：4

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