In situ characterization of catalysts active in partial oxidations:: TS-1 and Fe-MFI case studies

被引：43
作者：
Zecchina, A
Bordiga, S
Spoto, G
Damin, A
Berlier, G
Bonino, F
Prestipino, C
Lamberti, C
机构：
[1] Univ Turin, Dept Inorgan Phys & Mat Chem, I-10125 Turin, Italy
[2] Univ Turin, INSTM Res Unit, Turin, Italy
[3] Univ Turin, INFM UdR, Turin, Italy
来源：
TOPICS IN CATALYSIS | 2002年 / 21卷 / 1-3期
关键词：
TS-1; Fe-MFI; partial oxidation reactions; in situ spectroscopies;
D O I：
10.1023/A:1020504115146
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A concise review of the firmly established knowledge and of the unresolved problems concerning the structure and the reactivity of Ti and Fe sites in TS-1 and Fe-MFI partial oxidation catalysts is given. Some new experimental and theoretical results are also described.
引用
收藏
页码：67 / 78
页数：12
相关论文
共 111 条
[1]   Diastereoselective catalytic epoxidation of chiral allylic alcohols by the TS-1 and Ti-beta zeolites: Evidence for a hydrogen-bonded, peroxy-type loaded complex as oxidizing species [J].
Adam, W ;
Corma, A ;
Reddy, TI ;
Renz, M .
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (11) :3631-3637
[2]   EXAFS STUDIES OF IRON-SUBSTITUTED ZEOLITE ZSM-5 [J].
AXON, SA ;
FOX, KK ;
CARR, SW ;
KLINOWSKI, J .
CHEMICAL PHYSICS LETTERS, 1992, 189 (01) :1-6
[3]   ADDUCT FORMATION AND FURTHER REACTIVITY OF IRON CARBONYL-COMPLEXES INTRODUCED INTO A ZEOLITE MATRIX [J].
BALLIVETTKATCHENKO, D ;
COUDURIER, G .
INORGANIC CHEMISTRY, 1979, 18 (03) :558-564
[4]   INTERACTION BETWEEN ZEOLITES AND CLUSTER COMPOUNDS .2. THERMAL-DECOMPOSITION OF IRON PENTACARBONYL ON ZEOLITES [J].
BEIN, T ;
JACOBS, PA .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1984, 80 :1391-1407
[5]   REACTIONS OF TITANIUM SILICALITE WITH PROTIC MOLECULES AND HYDROGEN-PEROXIDE [J].
BELLUSSI, G ;
CARATI, A ;
CLERICI, MG ;
MADDINELLI, G ;
MILLINI, R .
JOURNAL OF CATALYSIS, 1992, 133 (01) :220-230
[6]  
BERLIER G, UNPUB J CATAL
[7]   Direct synthesis and characterization of hydrophobic aluminum-free Ti-beta zeolite [J].
Blasco, T ;
Camblor, MA ;
Corma, A ;
Esteve, P ;
Guil, JM ;
Martínez, A ;
Perdigón-Melón, JA ;
Valencia, S .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (01) :75-88
[8]   THE STATE OF TI IN TITANOALUMINOSILICATES ISOMORPHOUS WITH ZEOLITE-BETA [J].
BLASCO, T ;
CAMBLOR, MA ;
CORMA, A ;
PEREZPARIENTE, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (25) :11806-11813
[9]  
Boccuti M.R., 1989, STUD SURF SCI CATAL, P133
[10]   Heterogeneity of framework Ti(IV) in Ti-silicalite as revealed by the adsorption of NH3.: Combined calorimetric and spectroscopic study [J].
Bolis, V ;
Bordiga, S ;
Lamberti, C ;
Zecchina, A ;
Carati, A ;
Rivetti, F ;
Spanò, G ;
Petrini, G .
LANGMUIR, 1999, 15 (18) :5753-5764
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