Design and Synthesis of a Novel n-Type Polymer Based on Asymmetric Rylene Diimide for the Application in All-Polymer Solar Cells

被引：26

作者：

Yang, Jing ^{[1
,2
]}

Chen, Fan ^{[1
,2
]}

Ran, Huijuan ^{[3
]}

Hu, Jian-Yong ^{[3
]}

Xiao, Bo ^{[1
,2
]}

Tang, Ailing ^{[1
]}

Wang, Xiaochen ^{[1
]}

Zhou, Erjun ^{[1
]}

机构：

[1] Natl Ctr Nanosci & Technol, CAS Key Lab Nanosyst & Hierarch Fabricat, CAS Ctr Excellence Nanosci, Beijing 100190, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[3] Shaanxi Normal Univ, Shanxi Key Lab Adv Energy Devices, Sch Mat Sci & Engn, Xian 710119, Shaanxi, Peoples R China

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2018年 / 39卷 / 14期

基金：

中国国家自然科学基金;

关键词：

all-polymer solar cells (all-PSC); naphthalene diimide (NDI); non-fullerene acceptors; PTB7-Th; thianaphthene-fused perylenediimde (TDI); POWER CONVERSION EFFICIENCY; FIELD-EFFECT TRANSISTORS; NAPHTHALENE DIIMIDE; AMBIPOLAR SEMICONDUCTORS; ELECTRON-ACCEPTORS; PERYLENEDIIMIDE; COPOLYMERS; DONOR; SELENOPHENE; ABSORPTION;

D O I：

10.1002/marc.201700715

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A novel n-type polymer of PTDI-T based on asymmetric rylene diimide and thiophene is designed and synthesized. The highest power conversion efficiency of 4.70% is achieved for PTB7-Th: PTDI-T-based devices, which is obviously higher than those of the analogue polymers of PPDI-2T and PDTCDI. When using PBDB-T as a donor, an open-circuit voltage (V-OC) as high as 1.03 V is obtained. The results indicate asymmetric rylene diimide is a kind of promising building block to construct n-type photovoltaic polymers.

引用

页数：6

共 50 条

[1] Recent advances in rylene diimide polymer acceptors for all-polymer solar cells
Xin Guo
Dandan Tu
Xuan Liu
Journal of Energy Chemistry, 2015, (06) : 675 - 685
[2] Synthesis and application of poly(fluorene-alt-naphthalene diimide) as an n-type polymer for all-polymer solar cells
Zhou, Erjun
Cong, Junzi
Zhao, Mingxiu
Zhang, Luozheng
Hashimoto, Kazuhito
Tajima, Keisuke
CHEMICAL COMMUNICATIONS, 2012, 48 (43) : 5283 - 5285
[3] Recent advances in rylene diimide polymer acceptors for all-polymer solar cells
Guo, Xin
Tu, Dandan
Liu, Xuan
JOURNAL OF ENERGY CHEMISTRY, 2015, 24 (06) : 675 - 685
[4] Recent advances in rylene diimide polymer acceptors for all-polymer solar cells
Xin Guo
Dandan Tu
Xuan Liu
Journal of Energy Chemistry, 2015, 24 (06) : 675 - 685
[5] A low band gap n-type polymer based on dithienosilole and naphthalene diimide for all-polymer solar cells application
Geng, Yanfang
Huang, Jianming
Tajima, Keisuke
Zeng, Qingdao
Zhou, Erjun
POLYMER, 2015, 63 : 164 - 169
[6] n-Type Conjugated Polymer Based on Dicyanodistyrylbenzene and Naphthalene Diimide Units for All-Polymer Solar Cells
He, Baitian
Yin, Qingwu
Zhang, Jie
Jia, Tao
Yang, Xiye
Jiang, Xiao-Fang
Huang, Fei
Cao, Yong
CHINESE JOURNAL OF CHEMISTRY, 2018, 36 (05) : 406 - 410
[7] An amorphous N-type polymer based on perylenediimide and selenophene for all-polymer solar cells application
Wang, Xiaochen
Huang, Jianming
Tajima, Keisuke
Xiao, Bo
Zhou, Erjun
MATERIALS TODAY COMMUNICATIONS, 2015, 4 : 16 - 21
[8] New n-type polymer semiconductors for all-polymer solar cells
Hwang, Ye-Jin
Earmme, Taeshik
Murari, Nishit M.
Jenekhe, Samson A.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
[9] N-Type Quinoidal Polymers Based on Dipyrrolopyrazinedione for Application in All-Polymer Solar Cells
Pan, Langheng
Zhan, Tao
Oh, Jiyeon
Zhang, Yue
Tang, Haoran
Yang, Mingqun
Li, Mengmeng
Yang, Changduk
Liu, Xi
Cai, Ping
Duan, Chunhui
Huang, Fei
Cao, Yong
CHEMISTRY-A EUROPEAN JOURNAL, 2021, 27 (54) : 13527 - 13533
[10] Comparison among Perylene Diimide (PDI), Naphthalene Diimide (NDI), and Naphthodithiophene Diimide (NDTI) Based n-Type Polymers for All-Polymer Solar Cells Application
Yang, Jing
Xiao, Bo
Tajima, Keisuke
Nakano, Masahiro
Takimiya, Kazuo
Tang, Ailing
Zhou, Erjun
MACROMOLECULES, 2017, 50 (08) : 3179 - 3185

← 1 2 3 4 5 →