The Impact of Graphene and Diatomite Admixtures on the Performance and Properties of High-Performance Magnesium Oxychloride Cement Composites

被引:6
作者
Lauermannova, Anna-Marie [1 ]
Antoncik, Filip [1 ]
Lojka, Michal [1 ]
Jankovsky, Ondrej [1 ]
Pavlikova, Milena [2 ]
Pivak, Adam [2 ]
Zaleska, Martina [2 ]
Pavlik, Zbysek [2 ]
机构
[1] Univ Chem & Technol, Fac Chem Technol, Dept Inorgan Chem, Tech 5, Prague 16628, Czech Republic
[2] Czech Tech Univ, Fac Civil Engn, Dept Mat Engn & Chem, Thakurova 7, Prague 16629, Czech Republic
关键词
composites; magnesium oxychloride; sorel cement; graphene; diatomite; MECHANICAL-PROPERTIES; PARTIAL REPLACEMENT; AQUEOUS-SOLUTIONS; WATER RESISTANCE; GAS EMISSIONS; CONCRETE; CARBON; REMOVAL; POWDER; PHASES;
D O I
10.3390/ma13245708
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A high-performance magnesium oxychloride cement (MOC) composite composed of silica sand, diatomite powder, and doped with graphene nanoplatelets was prepared and characterized. Diatomite was used as a 10 vol.% replacement for silica sand. The dosage of graphene was 0.5 wt.% of the sum of the MgO and MgCl2 center dot 6H(2)O masses. The broad product characterization included high-resolution transmission electron microscopy, X-ray diffraction, X-ray fluorescence, scanning electron microscopy and energy dispersive spectroscopy analyses. The macrostructural parameters, pore size distribution, mechanical resistance, stiffness, hygric and thermal parameters of the composites matured for 28-days were also the subject of investigation. The combination of diatomite and graphene nanoplatelets greatly reduced the porosity and average pore size in comparison with the reference material composed of MOC and silica sand. In the developed composites, well stable and mechanically resistant phase 5 was the only precipitated compound. Therefore, the developed composite shows high compactness, strength, and low water imbibition which ensure high application potential of this novel type of material in the construction industry.
引用
收藏
页码:1 / 14
页数:14
相关论文
共 72 条
[11]   The use of waste ceramic tile in cement production [J].
Ay, N ;
Ünal, M .
CEMENT AND CONCRETE RESEARCH, 2000, 30 (03) :497-499
[12]  
Aytas SO, 1999, J RADIOANAL NUCL CH, V240, P973
[13]   Removal of lead(II) ions from aqueous solutions using diatomite nanoparticles [J].
Beheshti, Hoda ;
Irani, Mohammad .
DESALINATION AND WATER TREATMENT, 2016, 57 (40) :18799-18805
[14]  
BILINSKI H, 1984, J AM CERAM SOC, V67, P266
[15]   Graphene-based liquid crystal device [J].
Blake, Peter ;
Brimicombe, Paul D. ;
Nair, Rahul R. ;
Booth, Tim J. ;
Jiang, Da ;
Schedin, Fred ;
Ponomarenko, Leonid A. ;
Morozov, Sergey V. ;
Gleeson, Helen F. ;
Hill, Ernie W. ;
Geim, Andre K. ;
Novoselov, Kostya S. .
NANO LETTERS, 2008, 8 (06) :1704-1708
[16]   Toward graphene chloride: chlorination of graphene and graphene oxide [J].
Bousa, D. ;
Luxa, J. ;
Mazanek, V. ;
Jankovsky, O. ;
Sedmidubsky, D. ;
Klimova, K. ;
Pumera, M. ;
Sofer, Z. .
RSC ADVANCES, 2016, 6 (71) :66884-66892
[17]   Optimisation of magnesium oxychloride cement properties by silica glass [J].
Brichni, Amal ;
Hammi, Halim ;
Aggoun, Salima ;
Mnif, Adel .
ADVANCES IN CEMENT RESEARCH, 2016, 28 (10) :654-663
[18]   Temperature dependence of the Raman spectra of graphene and graphene multilayers [J].
Calizo, I. ;
Balandin, A. A. ;
Bao, W. ;
Miao, F. ;
Lau, C. N. .
NANO LETTERS, 2007, 7 (09) :2645-2649
[19]   The electronic properties of graphene [J].
Castro Neto, A. H. ;
Guinea, F. ;
Peres, N. M. R. ;
Novoselov, K. S. ;
Geim, A. K. .
REVIEWS OF MODERN PHYSICS, 2009, 81 (01) :109-162
[20]   Influences of fly ash on magnesium oxychloride mortar [J].
Chau, C. K. ;
Chan, James ;
Li, Zongjin .
CEMENT & CONCRETE COMPOSITES, 2009, 31 (04) :250-254