High-Efficient Oxidation-Extraction Desulfurization Process by Ionic Liquid 1-Butyl-3-methyl-imidazolium Trifluoroacetic Acid

被引：35

作者：

Fang, Dawei ^{[1
]}

Wang, Qiang ^{[2
]}

Liu, Yu ^{[1
]}

Xia, Lixin ^{[1
]}

Zang, Shuliang ^{[1
,2
]}

机构：

[1] Liaoning Univ, Coll Chem, Key Lab Rare & Scattered Elements, Shenyang 110036, Liaoning, Peoples R China

[2] Liaoning Shihua Univ, Sch Chem & Mat Sci, Fushun 113001, Liaoning, Peoples R China

来源：

ENERGY & FUELS | 2014年 / 28卷 / 10期

基金：

中国国家自然科学基金;

关键词：

OIL REFINERY STREAMS; DEEP DESULFURIZATION; SOLUTION ENTHALPIES; FUEL; CATALYSTS; SOLVENT; DIESEL; SYSTEM;

D O I：

10.1021/ef501675m

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

A Bronsted acid ionic liquid (IL), [C(4)mim]TFA (1-butyl-3-methyl-imidazolium trifluoroacetic acid), was synthesized and used as an extractant and catalyst for oxidation desulfurization (ODS) of thiophene from model oil with hydrogen peroxide as the oxidant. The major factors of the reaction were investigated in detail. The effect of different types of ILs on oxidative and extractive desulfurization capacities of model oil was tested, which proved TFA(-) > HSO4- > COO- > AlCl4- > AcO-. The reaction heat caused by H2O2 dissolved in IL was determined by a calorimeter.

引用

页码：6677 / 6682

页数：6

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