Mechanistic aspects of copper (II)-catalyzed synthesis of sulfones from sulfinate salts and aryl halides under C-S coupling

被引：9

作者：

Ge, Xin ^{[1
,2
]}

Sun, Fengli ^{[1
]}

Liu, Xuemin ^{[1
]}

Chen, Xinzhi ^{[2
]}

Qian, Chao ^{[2
]}

Zhou, Shaodong ^{[2
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Wuxi, Peoples R China

[2] Zhejiang Univ, Coll Chem & Biol Engn, Minist Educ, Key Lab Biomass Chem Engn, Hangzhou, Zhejiang, Peoples R China

来源：

MOLECULAR CATALYSIS | 2018年 / 449卷

基金：

中国博士后科学基金;

关键词：

Copper; C-S coupling reaction; in-situ IR; Mechanism; DFT; ACID SALTS; BIOLOGICAL EVALUATION; CATALYZED SYNTHESIS; ULLMANN REACTION; DIARYL SULFONES; D-GLUCOSAMINE; COMPLEXES; IODIDES; LIGAND; METAL;

D O I：

10.1016/j.mcat.2017.12.016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Copper(II)-catalyzed synthesis of sulfones from sulfinate salts and aryl halides was investigated by means of a combination of experiment and DFT calculation. Experimental results demonstrated the wide applicability of the title approach. The reaction mechanisms are revealed by in-situ IR and theoretical study. It reveals remarkable ligand effect the bidentate amine plays in the reaction, that is, it initially activats the C-I bond of iodobenzene so as to enhance the whole catalytic process. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：72 / 78

页数：7

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