Surface modifications of PADC polymeric material by ion beam bombardment for high technology applications

被引：18
作者：
Abdul-Kader, A. M. [1 ,2 ]
机构：
[1] Helwan Univ, Fac Sci, Dept Phys, Cairo, Egypt
[2] Umm Al Qura Univ, Univ Coll, Dept Phys, Al Qunfoza, Saudi Arabia
来源：
RADIATION MEASUREMENTS | 2014年 / 69卷
关键词：
PADC; Ion beam; Optical properties; Surface free energy; Surface hardness; CARBONACEOUS CLUSTERS; IRRADIATED POLYMERS; HYDROGEN RELEASE; MAKROFOL-KG; ANGLE; RAY;
D O I：
10.1016/j.radmeas.2014.07.013
中图分类号：
TL [原子能技术]; O571 [原子核物理学];
学科分类号：
0827 ; 082701 ;
摘要：
Surface modification of Poly (allyl diglycol carbonate) (PADC) is induced by 150 keV Ag ions of different fluences. The pristine as well as bombarded samples were investigated by UV-Vis spectroscopy, Fourier transform-infrared analysis (FTIR) and micro-hardness tester. The variations of wettability and surface free energy were determined by the contact angle measurements. The obtained results showed that ion beam bombardment induced increase in the absorption spectra of the UV-Vis with increase of ion fluence as well. The direct and indirect optical band gap decreased from 4.2 to 3.6 eV for pristine sample to 3.2 and 2.5 eV for those bombarded with Ag ion beam at the highest fluence, respectively. Changes in chemical properties were observed by Fourier transform infrared spectroscopy. Increase in the wettability, surface free energy and work of adhesion with increase the ion fluence were observed. Ion bombardment inducing increasing in a micro-hardness surface due to the high carbon surface concentration and cross-linking effects in the polymeric chains. The bombarded PADC surfaces may find special applications to the field of the micro-electronic devices and printing process. (C) 2014 Elsevier Ltd. All rights reserved.
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页码：1 / 6
页数：6
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