Nanoscale Phase Separation in Lithium Niobium Silicate Glass by Femtosecond Laser Irradiation

被引:47
作者
Cao, Jing [1 ]
Poumellec, Bertrand [1 ]
Mazerolles, Leo [2 ]
Brisset, Francois [1 ]
Helbert, Anne-Laure [1 ]
Surble, Suzy [3 ]
He, Xuan [4 ]
Lancry, Matthieu [1 ]
机构
[1] Univ Paris Saclay, Univ Paris Sud, Inst Chim Mol & Mat Orsay,CNRS,UPSud, Synth Propriete & Modelisat Mat, Orsay, France
[2] Univ Paris Est, CNRS, Inst Chim & Mat Paris Est, UMR 7182, Thiais, France
[3] Univ Paris Saclay, CNRS, CEA, LEEL,NIMBE, Gif Sur Yvette, France
[4] Wuhan Univ Sci & Technol, State Key Lab Refractories & Met, Wuhan, Peoples R China
关键词
crystals/crystallization; glass-ceramics; nanomaterials; optical materials/properties; phase separation; 2ND-HARMONIC GENERATION; INDUCED NANOGRATINGS; ULTRAFAST LASER; FUSED-SILICA; CRYSTALLIZATION; CRYSTALS;
D O I
10.1111/jace.14570
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Understanding the phase transformation in glass and the morphology of related nanostructure after femtosecond laser irradiation is of great importance for fabricating functional optics, in which glass crystallization is involved to obtain nonlinear optical properties. We report on the crystallization inside lithium niobium silicate glass induced by fs laser irradiation. Energy-dispersive X-ray spectroscopy coupled to scanning transmission electron microscopy (STEM/EDS) and transmission electron microscopy confirm a nanoscale phase separation whereby LiNbO3 crystals are embedded in lamella-shaped frames of amorphous SiO2. The obtained nanostructure may have applications in fabricating second-order nonlinear optical devices.
引用
收藏
页码:115 / 124
页数:10
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