Synthesis of TS-1 Films on Porous Supports for Epoxidation of Allyl Chloride by Hydrogen Peroxide

被引：0

作者：

Gu Ling ^{[1
,2
]}

Wang Li ^{[2
]}

机构：

[1] Shanxi Datong Univ, Sch Chem & Environm Engn, Datong 037009, Peoples R China

[2] Tianjin Univ, Key Lab Green Chem Technol, Minist Educ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China

来源：

CHINA PETROLEUM PROCESSING & PETROCHEMICAL TECHNOLOGY | 2013年 / 15卷 / 03期

关键词：

TS-1; film; epoxidation; epichlorohydrin; TITANIUM SILICALITE; MEMBRANES; NORBORNADIENE; ZEOLITE; METAL; ISOMERIZATION; QUADRICYCLANE; TI; OPTIMIZATION; PROPYLENE;

D O I：

暂无

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Titanium silicalite-1 (TS-1) films were synthesized on stainless steel plate, glass slide and monolith supports via an in-situ hydrothermal method. Characterization data showed that the formation of TS-1 films was easier on the porous flat support with rough surface such as monolith than on the smooth non-porous supports like glass slide and stainless steel plate. The film on the monolith had the highest uniformity and smallest size of crystals. The catalytic property of monolith-supported film was tested for epoxidation of allyl chloride (ACH) by H2O2 in a fixed bed reactor. Under the condition of a methanol (solvent)/ACH (90%)/H2O2 (30%) ratio of 12:1:1, a LHSV of 1.35 h(-1) and a temperature of 318 K, the conversion of allyl chloride and the selectivity to epichlorohydrin reached 79 % and 51 %, respectively.

引用

页码：45 / 49

页数：5

共 50 条

[31] The epoxidation of diallyl ether to allyl-glycidyl ether over the TS-1 catalyst
A. Wróblewska
E. Drewnowska
A. Gawarecka
Reaction Kinetics, Mechanisms and Catalysis, 2016, 118 : 719 - 731
[32] Influence of Pt-Pd/TS-1 catalyst preparation on epoxidation of olefins with hydrogen peroxide
Wang, QF
Wang, L
Mi, ZT
CATALYSIS LETTERS, 2005, 103 (1-2) : 161 - 164
[33] Kinetics of allyl chloride epoxidation with hydrogen peroxide catalyzed by extruded titanium silicalite
A. V. Sulimov
S. M. Danov
A. V. Ovcharova
A. A. Ovcharov
V. R. Flid
Kinetics and Catalysis, 2014, 55 : 712 - 721
[34] Size effect of TS-1 supports on the catalytic performance of PtSn/TS-1 catalysts for propane dehydrogenation
Li, Jiacheng
Li, Jianmei
Zhao, Zhen
Fan, Xiaoqiang
Liu, Jian
Wei, Yuechang
Duan, Aijun
Xie, Zean
Liu, Qinglong
JOURNAL OF CATALYSIS, 2017, 352 : 361 - 370
[35] The effects of impregnation of precious metals on the catalytic activity of titanium silicate (TS-1) in epoxidation of propene using hydrogen peroxide
Shin, Sang Baek
Lee, Dae-Won
Chadwick, David
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2016, 423 : 478 - 488
[36] Selective epoxidation of styrene to styrene oxide over TS-1 using urea-hydrogen peroxide as oxidizing agent
Laha, SC
Kumar, R
JOURNAL OF CATALYSIS, 2001, 204 (01) : 64 - 70
[37] Effect of Sodium Ions on Catalytic Performance of TS-1 in Gas-Phase Epoxidation of Propylene with Hydrogen Peroxide Vapor
Miao, Cuilan
He, Ning
Zhu, Quanren
Yi, Yanhui
Feng, Zhaochi
Guo, Hongchen
CATALYSIS LETTERS, 2020, 150 (01) : 281 - 290
[38] Epoxidation of allyl choride with molecular oxygen and 2-ethyl-anthrahydroquinone catalyzed by TS-1
Wang, QF
Mi, ZT
Wang, YQ
Wang, L
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 229 (1-2) : 71 - 75
[39] Solvent Effects in Epoxidation of Fatty Acid Methyl Esters with Hydrogen Peroxide over TS-1 Catalyst
Esipovich, A. L.
Belousov, A. S.
Kanakov, E. A.
Mironova, V. Yu.
Rogozhin, A. E.
Danov, S. M.
Vorotyntsev, A. V.
Makarov, D. A.
KINETICS AND CATALYSIS, 2019, 60 (01) : 62 - 68
[40] Solvent Effects in Epoxidation of Fatty Acid Methyl Esters with Hydrogen Peroxide over TS-1 Catalyst
A. L. Esipovich
A. S. Belousov
E. A. Kanakov
V. Yu. Mironova
A. E. Rogozhin
S. M. Danov
A. V. Vorotyntsev
D. A. Makarov
Kinetics and Catalysis, 2019, 60 : 62 - 68

← 1 2 3 4 5 →