Luminescence and energy transfer of the color-tunable phosphor Li6Gd(BO3)3:Tb3+/Bi3+, Eu3+

被引:15
作者
Chen, Peican [1 ]
Mo, Fuwang [1 ]
Guan, Anxiang [1 ]
Wang, Rongfang [2 ]
Wang, Guofang [1 ]
Xi, Siyu [1 ]
Zhou, Liya [1 ]
机构
[1] Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China
[2] Yulin Normal Univ, Guangxi Key Lab Agr Prod Proc, Coll Chem & Mat,Cultivating Base, Coll & Univ Key Lab Efficient Use Agr Resources S, Yulin 537000, Guangxi, Peoples R China
基金
中国国家自然科学基金;
关键词
Luminescence; Phosphor; Optical properties; PHOTOLUMINESCENCE PROPERTIES; RED EMISSION; LIGHT; SYSTEM; FIELD; TB3+;
D O I
10.1016/j.apradiso.2015.12.042
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Bi3+/Tb3+, Eu3+ co-doped Li6Gd(BO3)(3) (LGBO) phosphors were synthesized via a traditional solid-state method. Phase purity was investigated using X-ray diffraction, absorption strength of the phosphors were investigated by UV-vis absorption spectra, and the photoluminescence properties of the phosphors were studied systematically. Results showed that the emission intensity of Bi3+, Eu3+ co-doped LBOG was 2.76 times higher than that of Eu3+-doped LGBO irradiated at 275 nm, thereby implying the possibility of energy transfer from Bi3+ to Eu3+. The excitation spectra of Tb3+, Eu3+ co-doped LGBO phosphors are broader in comparison with single-doped phosphors and show tunable colors from green to yellow to orange-red when the ratio of Tb3+ to Eu3+ is adjusted These results demonstrate that LGBO:Tb3+, Eu3+ phosphors have potential use in light-emitting diodes. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:148 / 153
页数:6
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