Bioelectrocatalytic hydrogen production by hydrogenase electrodes

被引：39

作者：

Morozov, SV ^{[1
]}

Vignais, PM

Cournac, VL

Zorin, NA

Karyakina, EE

Karyakin, AA

Cosnier, S

机构：

[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119992, Russia

[2] CEA Grenoble, Dept Biol Mol & Struct, Lab Biochim & Biophys Syst Integres, CNRS,UMR 5092,UJF, F-38054 Grenoble 9, France

[3] Univ Mediterranee, CNRS, Dept Ecophysiol Vegetale & Microbiol, CEA Cadarache,Lab Ecophysiol Photosintese,UMR 16, F-13108 St Paul Les Durance, France

[4] Russian Acad Sci, Inst Basic Biol Problems, Pushchino 142190, Moscow Region, Russia

[5] Univ Grenoble 1, CNRS, Lab Electrochim Organ & Photochim Redox, UMR 5630, F-38041 Grenoble 9, France

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2002年 / 27卷 / 11-12期

关键词：

hydrogenase; hydrogen production; direct bioelectrocatalysis; enzyme electrodes; poly(pyrrole);

D O I：

10.1016/S0360-3199(02)00091-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Production of molecular hydrogen by enzyme electrodes based on direct bioelectrocatalysis by [NiFe] hydrogenases from different sources (Thiocapsa roseopersicina and Desulfovibrio fructosovorans) was investigated. Hydrogen evolution was independently controlled by means of mass spectrometry. A strong correlation between the cathodic current generated by the hydrogenase electrodes and the rate of hydrogen evolution was demonstrated. (C) 2002 International Association for Hydrogen Energy. Published by Elsevier Science Ltd. All rights reserved.

引用

页码：1501 / 1505

页数：5

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