Infinite 1D water chains present in complexes of Co(II) and Zn(II) with 4,4',6,6'-tetramethyl-2,2'-bipyrimidine

被引：0

作者：

Ma, N. ^{[1
]}

Ji, B. M. ^{[1
]}

机构：

[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 55卷 / 03期

基金：

中国国家自然科学基金;

关键词：

complex; Co(II); Zn(II); tmbpm; crystal structure; intermolecular hydrogen bond; water chain; ONE-DIMENSIONAL WATER; CLUSTER; IDENTIFICATION; DYNAMICS; CHANNEL; CU(II); TRIMER;

D O I：

10.1134/S0022476614030263

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new transition metal complexes [Co(tmbpm)Cl-2(H2O)]center dot 2H(2)O (1) and [Zn(tmbpm)Cl-2]center dot 2H(2)O (2) (where tmbpm = 4,4',6,6'-tetramethyl-2,2'-bipyrimidine) are synthesized and characterized by IR and single crystal X-ray diffraction. The tmbpm adopts chelating coordination mode in the two mononuclear complexes. Both 1 and 2 form 2D supramolecular structures containing an infinite 1D water chain through hydrogen bonds.

引用

页码：564 / 569

页数：6