Infinite 1D water chains present in complexes of Co(II) and Zn(II) with 4,4',6,6'-tetramethyl-2,2'-bipyrimidine

被引：0
|
作者：
Ma, N. [1 ]
Ji, B. M. [1 ]
机构：
[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 55卷 / 03期
基金：
中国国家自然科学基金;
关键词：
complex; Co(II); Zn(II); tmbpm; crystal structure; intermolecular hydrogen bond; water chain; ONE-DIMENSIONAL WATER; CLUSTER; IDENTIFICATION; DYNAMICS; CHANNEL; CU(II); TRIMER;
D O I：
10.1134/S0022476614030263
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new transition metal complexes [Co(tmbpm)Cl-2(H2O)]center dot 2H(2)O (1) and [Zn(tmbpm)Cl-2]center dot 2H(2)O (2) (where tmbpm = 4,4',6,6'-tetramethyl-2,2'-bipyrimidine) are synthesized and characterized by IR and single crystal X-ray diffraction. The tmbpm adopts chelating coordination mode in the two mononuclear complexes. Both 1 and 2 form 2D supramolecular structures containing an infinite 1D water chain through hydrogen bonds.
引用
收藏
页码：564 / 569
页数：6
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