Gasoline from Biomass through Refinery-Friendly Carbohydrate-Based Bio-Oil Produced by Ketalization

被引：21

作者：

Batalha, Nuno ^{[1
]}

da Silva, Alessandra V. ^{[1
]}

de Souza, Matheus O. ^{[1
]}

da Costa, Bruna M. C. ^{[1
]}

Gomes, Elisa S. ^{[1
]}

Silva, Thiago C. ^{[1
]}

Barros, Thalita G. ^{[1
]}

Goncalves, Maria L. A. ^{[1
]}

Caramao, Elina B. ^{[2
,3
]}

dos Santos, Luciana R. M. ^{[4
]}

Almeida, Marlon B. B. ^{[4
]}

de Souza, Rodrigo O. M. A. ^{[1
]}

Lam, Yiu L. ^{[4
]}

Carvalho, Nakedia M. F. ^{[5
]}

Miranda, Leandro S. M. ^{[1
]}

Pereira, Marcelo M. ^{[1
]}

机构：

[1] Univ Fed Rio de Janeiro, Inst Quim, Ctr Tecnol, BR-21949909 Rio De Janeiro, RJ, Brazil

[2] Univ Fed Rio Grande do Sul, Inst Quim, BR-91501970 Porto Alegre, RS, Brazil

[3] INCT EA Energia Ambiente, Rio De Janeiro, Brazil

[4] Ctr Pesquisas & Desenvolvimento Leopoldo A Miguez, Tecnol FCC Petrobras, BR-21941598 Rio De Janeiro, RJ, Brazil

[5] Univ Estado Rio de Janeiro, Inst Quim, BR-20550013 Rio De Janeiro, RJ, Brazil

来源：

CHEMSUSCHEM | 2014年 / 7卷 / 06期

关键词：

biomass; carbohydrates; cracking; hydrolysis; isotopic labeling; PYROLYSIS OIL; CATALYTIC CRACKING; HYDROCARBONS; CONVERSION; HYDROGEN; FUELS; CO; HYDROLYSIS; FEEDSTOCKS; LIQUIDS;

D O I：

10.1002/cssc.201301242

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The introduction of biomass-derived compounds as an alternative feed into the refinery structure that already exists can potentially converge energy uses with ecological sustainability. Herein, we present an approach to produce a bio-oil based on carbohydrate-derived isopropylidene ketals obtained by reaction with acetone under acidic conditions directly from second-generation biomass. The obtained bio-oil showed a greater chemical inertness and miscibility with gasoil than typical bio-oil from fast pyrolysis. Catalytic upgrading of the bio-oil over zeolites (USY and Beta) yielded gasoline with a high octane number. Moreover, the co-processing of gasoil and bio-oil improved the gasoline yield and quality compared to pure gasoil and also reduced the amount of oxygenated compounds and coke compared with pure bio-oil, which demonstrates a synergistic effect.

引用

页码：1627 / 1636

页数：10

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