Phase separation process preventing thermal embrittlement of a Zr-Cu-Fe-Al bulk metallic glass

被引:33
作者
Louzguine-Luzgin, D. V. [1 ,2 ]
Jiang, J. [3 ]
Bazlov, A. I. [4 ]
Zolotorevzky, V. S. [4 ]
Mao, H. [5 ,6 ]
Ivanov, Yu P. [7 ]
Greer, A. L. [1 ,7 ]
机构
[1] Tohoku Univ, WPI Adv Inst Mat Res, Sendai, Miyagi 9808577, Japan
[2] Natl Inst Adv Ind Sci & Technol, Math Adv Mat OIL, Sendai, Miyagi 9808577, Japan
[3] Tohoku Univ, Grad Sch Engn, Sendai, Miyagi 9808577, Japan
[4] Natl Univ Sci & Technol MISiS, Moscow 119049, Russia
[5] KTH Royal Inst Technol, Dept Mat Sci & Engn, S-10044 Stockholm, Sweden
[6] Thermo Calc Software AB, Rasundavagen 18, S-16967 Solna, Sweden
[7] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB3 0FS, England
基金
欧洲研究理事会;
关键词
Bulk metallic glass; Mechanical properties; Relaxation; Phase separation; Transmission electron microscopy; STRUCTURAL RELAXATION; DEFORMATION-BEHAVIOR; THERMODYNAMIC ASSESSMENT; MECHANICAL-PROPERTIES; SUPERCOOLED LIQUID; AMORPHOUS-PHASE; FORMING ABILITY; SHEAR BANDS; ALLOYS; MICROSTRUCTURE;
D O I
10.1016/j.scriptamat.2019.03.030
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The structural changes and mechanical properties of a Zr63Cu22Fe5Al10 bulk metallic glass (BMG), and a Zr63Cu27Al10 one made for comparison, were studied on annealing below the crystallization temperature. The phase composition of the samples was studied by conventional X-ray diffractometry and high-resolution transmission electron microscopy including the atomic-scale elemental mapping. The samples were mechanically tested in compression. The Zr63Cu22Fe5Al10 bulk metallic glass shows a high strength and good deformability at room temperature both in the as-cast state and after prolonged structural relaxation below the crystallization temperature. The reasons for such behavior are discussed in the present work. (C) 2019 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:31 / 36
页数:6
相关论文
共 55 条
[1]   Evolution of the amorphous-phase structure in metal–metal type metallic glasses [J].
Abrosimova G.E. ;
Aronin A.S. .
Journal of Surface Investigation, 2015, 9 (05) :887-893
[2]   Phase transformations in Zr-based bulk metallic glass cyclically loaded before plastic yielding [J].
Churyumov, A. Yu. ;
Bazlov, A. I. ;
Zadorozhnyy, V. Yu. ;
Solonin, A. N. ;
Caron, A. ;
Louzguine-Luzgin, D. V. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2012, 550 :358-362
[3]   Origin of embrittlement in metallic glasses [J].
Garrett, Glenn R. ;
Demetriou, Marios D. ;
Launey, Maximilien E. ;
Johnson, William L. .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2016, 113 (37) :10257-10262
[4]   Interaction of deformation shear bands with nanoparticles in amorphous-nanocrystalline alloys [J].
Glezer A.M. ;
Shurygina N.A. ;
Zaichenko S.G. ;
Permyakova I.E. .
Russian Metallurgy (Metally), 2013, 2013 (4) :235-244
[5]   New horizons for glass formation and stability [J].
Greer, A. Lindsay .
NATURE MATERIALS, 2015, 14 (06) :542-546
[6]   Combined effect of isothermal annealing and pre-compression on mechanical properties of Cu36Zr48Al8Ag8 bulk metallic glass [J].
Gu, Ji ;
Zhang, Li-xin ;
Wang, Yi-han ;
Ni, Song ;
Guo, Sheng-feng ;
Song, Min .
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2016, 26 (06) :1620-1628
[7]   Unusual plasticization for structural relaxed bulk metallic glass [J].
Guo, Wei ;
Yamada, Rui ;
Saida, Junji .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2017, 699 :81-87
[8]   Bulk metallic glass casting investigated using high-speed infrared monitoring and complementary fast scanning calorimetry [J].
Haag, Fabian ;
Geisel, Steffen ;
Kurtuldu, Guven ;
Loffler, Jorg F. .
ACTA MATERIALIA, 2018, 151 :416-423
[9]   Comparison of Structural Relaxation Behavior in As-Cast and Pre-Annealed Zr-Based Bulk Metallic Glasses Just below Glass Transition [J].
Haruyama, Osami ;
Yoshikawa, Kazuyoshi ;
Yamazaki, Yoshikatsu ;
Yokoyama, Yoshihiko ;
Egami, Takeshi .
MATERIALS TRANSACTIONS, 2015, 56 (05) :648-654
[10]   Thermodynamic assessment of the Ag-Zr and Cu-Zr binary systems [J].
Hsiao, Hsien-Ming ;
Liang, Song-Mao ;
Schmid-Fetzer, Rainer ;
Yen, Yee-wen .
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2016, 55 :77-87