Microstructure evolution of the 1469 Al-Cu-Li-Sc alloy during homogenization

被引:89
作者
Jia, Min [1 ]
Zheng, Ziqiao [1 ]
Gong, Zhu [1 ]
机构
[1] Cent S Univ, Sch Mat Sci & Engn, Changsha 410083, Peoples R China
关键词
Aluminum alloy; Sc; W phase; Segregation; Homogenization; EPMA; ALUMINUM-ALLOYS; SOLIDIFICATION BEHAVIOR; MECHANICAL-PROPERTIES; AL(SC) ALLOYS; MINOR SC; SCANDIUM; ZR; PRECIPITATION; ADDITIONS; SYSTEM;
D O I
10.1016/j.jallcom.2014.06.033
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The present work aims to clarify the formation of the W phase (AlCuSc) and its formation time in the high Cu content alloy with Sc addition. The microstructure evolution during the two-step homogenization annealing process was investigated in the 1469 Al-Cu-Li-Sc alloy. No evidences of the Al3Sc phase and the W phase were found in the solidification structure. The arrays of the W phases were found to form after homogenization. The AlCu phases with traces of Sc that formed during solidification suppose to be the precursor of the W phases, and then transform into the W phases by consuming the Sc atoms that fixed in the supersaturate solid solution. The formation of the W phase inhibits the precipitation of the Al3Sc phase. A corresponding model of the W phase formation mechanism is proposed. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:131 / 139
页数:9
相关论文
共 37 条
[1]   The properties and application of scandium-reinforced aluminum [J].
Ahmad, Z .
JOM-JOURNAL OF THE MINERALS METALS & MATERIALS SOCIETY, 2003, 55 (02) :35-39
[2]   Thermodynamic analysis of Al-Sc, Cu-Sc and Al-Cu-Sc system [J].
Bo, H. ;
Liu, L. B. ;
Jin, Z. P. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 490 (1-2) :318-325
[3]   Coarsening resistance at 400 °C of precipitation-strengthened Al-Zr-Sc-Er alloys [J].
Booth-Morrison, Christopher ;
Dunand, David C. ;
Seidman, David N. .
ACTA MATERIALIA, 2011, 59 (18) :7029-7042
[4]   Effect of interfacial solute segregation on ductile fracture of Al-Cu-Sc alloys [J].
Chen, B. A. ;
Liu, G. ;
Wang, R. H. ;
Zhang, J. Y. ;
Jiang, L. ;
Song, J. J. ;
Sun, J. .
ACTA MATERIALIA, 2013, 61 (05) :1676-1690
[5]   Alloying aluminum alloys with scandium and zirconium additives [J].
Davydov, VG ;
Elagin, VI ;
Zakharov, VV ;
Rostova, TD .
METAL SCIENCE AND HEAT TREATMENT, 1996, 38 (7-8) :347-352
[6]   Scientific principles of making an alloying addition of scandium to aluminium alloys [J].
Davydov, VG ;
Rostova, TD ;
Zakharov, VV ;
Filatov, YA ;
Yelagin, VI .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2000, 280 (01) :30-36
[7]   Effects of Sc and Zr microalloying additions on the microstructure and mechanical properties of new Al-Zn-Mg alloys [J].
Deng, Ying ;
Yin, Zhimin ;
Zhao, Kai ;
Duan, Jiaqi ;
He, Zhenbo .
JOURNAL OF ALLOYS AND COMPOUNDS, 2012, 530 :71-80
[8]   Evolution of precipitates in AlLiCu and AlLiCuSe alloys after age-hardening treatment [J].
Dutkiewicz, J ;
Simmich, O ;
Scholz, R ;
Ciach, R .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1997, 234 :253-257
[9]   High-strength structural silver-alloyed underdensity Al-Cu-Li-Mg alloy [J].
Fridlyander, I. N. ;
Grushko, O. E. ;
Shamrai, V. F. ;
Klochkov, G. G. .
METAL SCIENCE AND HEAT TREATMENT, 2007, 49 (5-6) :279-283
[10]   Solidification behaviour and the effects of homogenisation on the structure of an Al-Cu-Mg-Ag-Sc alloy [J].
Gazizov, Marat ;
Teleshov, Viktor ;
Zakharov, Valerij ;
Kaibyshev, Rustam .
JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (39) :9497-9507