Solution-Based Evolution and Enhanced Methanol Oxidation Activity of Monodisperse Platinum-Copper Nanocubes

被引：359

作者：

Xu, Dan ^{[1
]}

Liu, Zhaoping ^{[3
]}

Yang, Hongzhou ^{[2
]}

Liu, Qingsheng ^{[4
]}

Zhang, Jun ^{[1
]}

Fang, Jiye ^{[1
]}

Zou, Shouzhong ^{[2
]}

Sun, Kai ^{[5
]}

机构：

[1] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA

[2] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA

[3] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315211, Zhejiang, Peoples R China

[4] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

[5] Univ Michigan, Dept Mat Sci & Engn, Ann Arbor, MI 48109 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 23期

关键词：

alloys; copper; methanol electrooxidation; nanostructures; platinum; SHAPE-CONTROLLED SYNTHESIS; TRANSMISSION-ELECTRON-MICROSCOPY; OXYGEN REDUCTION; CATALYTIC-ACTIVITY; ALLOY; NANOPARTICLES; NANOCRYSTALS; SURFACE; GROWTH; CO;

D O I：

10.1002/anie.200900293

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Shape-controlled catalysis: High-quality Pt-Cu nanocubes with an average size of about 8 nm (see picture, scale bar=20 nm) were synthesized from a high-temperature organic solution system in the presence of various capping ligands. These cubic Pt-Cu nanocrystals terminated with {100} facets demonstrated a superior catalytic activity towards methanol oxidation compared to similar sized Pt-Cu and Pt nanospheres. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4217 / 4221

页数：5

共 55 条

[1] Shape-controlled synthesis of colloidal platinum nanoparticles [J].