Resolution equations for high-field ion mobility

被引:34
作者
Verbeck, GF [1 ]
Ruotolo, BT [1 ]
Gillig, KJ [1 ]
Russell, DH [1 ]
机构
[1] Texas A&M Univ, Dept Chem, Lab Biol Mass Sepctrometry, College Stn, TX 77843 USA
基金
美国国家科学基金会;
关键词
D O I
10.1016/j.jasms.2004.06.005
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
An extension of current mobility resolution equations as they apply to high-field ion mobility spectrometry is presented. The new resolution expression is applied to arrival time distributions for ions having a large range of ion mobilities and mass-to-charge ratios (m/z). The results indicate that the new equation can be utilized to predict the mobility resolution over a broader range of applied electric fields than previous ion mobility resolution expressions. (C) 2004 American Society for Mass Spectrometry.
引用
收藏
页码:1320 / 1324
页数:5
相关论文
共 30 条
[1]   Using different drift cases to change separation factors (α) in ion mobility spectrometry [J].
Asbury, GR ;
Hill, HH .
ANALYTICAL CHEMISTRY, 2000, 72 (03) :580-584
[2]  
Asbury GR, 2000, J MICROCOLUMN SEP, V12, P172, DOI 10.1002/(SICI)1520-667X(2000)12:3<172::AID-MCS7>3.0.CO
[3]  
2-W
[4]   Development of a Fourier-transform ion cyclotron resonance mass spectrometer-ion mobility spectrometer [J].
Bluhm, BK ;
Gillig, KJ ;
Russell, DH .
REVIEW OF SCIENTIFIC INSTRUMENTS, 2000, 71 (11) :4078-4086
[5]  
CARR TW, 1984, PLASMA CHROMATOGRAPH, P1
[6]  
Clemmer DE, 1997, J MASS SPECTROM, V32, P577
[7]  
COUTERMAN AE, 2001, J AM CHEM SOC, V123, P1490
[8]  
Crank J., 1975, MATH DIFFUSION, V2nd, P1
[9]  
EICEMAN GA, 1994, MOBILITY SPECTROMETR, P1
[10]  
GILLIG KJ, UNPUB