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Green polymer chemistry: new methods of polymer synthesis using renewable starting materials
被引:33
作者:
Kobayashi, Shiro
[1
]
机构:
[1] Kyoto Inst Technol, Ctr Fiber & Text Sci, Sakyo Ku, Kyoto 6068585, Japan
基金:
巴西圣保罗研究基金会;
关键词:
Green polymer chemistry;
Lactic acid;
Itaconic anhydride;
Renewable plant oils;
Cardanol;
Lipase enzyme;
RING-OPENING POLYMERIZATION;
LIPASE-CATALYZED SYNTHESIS;
L-LACTIC ACID;
ENZYMATIC POLYMERIZATION;
POLY(L-LACTIC ACID);
POLYESTER SYNTHESIS;
ITACONIC ANHYDRIDE;
POLY(LACTIC ACID);
PLANT OILS;
POLYCONDENSATION;
D O I:
10.1007/s11224-016-0861-3
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
The present article reviews the recent results reported mainly from our group on "green polymer chemistry". Characteristic important aspects of green polymer chemistry include herein, typically (1) using renewable resources as starting materials for polymer production, and (2) employing green method for the polymer synthesis. As renewable starting materials, the following materials were employed; lactic acid, itaconic anhydride, renewable plant oils, and cardanol. Polymer production using these materials contributes to mitigate the carbon dioxide emission because of their "carbon neutral" nature. As green method, lipase enzyme was mainly used for polymerization catalyst, since lipase is a natural benign catalyst, showing a specific catalysis as well as recyclable character. Polymer synthesis from these materials and the catalyst provided various value-added functional polymers, demonstrating good examples of green polymer chemistry.
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页码:461 / 474
页数:14
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