Synthesis of hexagonal boron carbonitride phase by solvothermal method

被引：65

作者：

Huang, FL ^{[1
]}

Cao, CB ^{[1
]}

Xiang, X ^{[1
]}

Lv, RT ^{[1
]}

Zhu, HS ^{[1
]}

机构：

[1] Beijing Inst Technol, Res Ctr Mat Sci, Beijing 100081, Peoples R China

来源：

基金：

中国国家自然科学基金;

关键词：

BCN; solvothermal synthesis; high pressure crystal growth; metastable phases;

D O I：

10.1016/j.diamond.2004.03.001

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A solvothermal reaction of CH3CN.BCl3 and lithium nitride (Li3N) using benzene as the solvent has been successfully applied to prepare boron carbonitride at 300 degreesC and less than about 7 MPa. X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) are used to confirm their chemical composition and atomic-level hybrid. X-ray diffraction (XRD) and transmission electron diffraction (TED) analysis indicate that the powders have hexagonal network structures. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：1757 / 1760

页数：4

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