Hydrogen evolution assisted electrodeposition of porous Cu-Ni alloy electrodes and their use for nitrate reduction in alkali

被引：89

作者：

Mattarozzi, Luca ^{[1
]}

Cattarin, Sandro ^{[1
]}

Comisso, Nicola ^{[1
]}

Gambirasi, Arianna ^{[1
]}

Guerriero, Paolo ^{[1
]}

Musiani, Marco ^{[1
]}

Vazquez-Gomez, Lourdes ^{[1
]}

Verlato, Enrico ^{[1
]}

机构：

[1] CNR, Ist Energet & Interfasi IENI, I-35127 Padua, Italy

来源：

ELECTROCHIMICA ACTA | 2014年 / 140卷

关键词：

Templated Electrodeposition; Bubble Template; Porous Alloy; Electrocatalysis; Nitrate; ELECTROCHEMICAL REDUCTION; SODIUM-HYDROXIDE; COPPER; DEPOSITION; NANOWIRES; ELECTROCATALYSIS; PLATINUM; CATHODES; NITRITE; ARRAYS;

D O I：

10.1016/j.electacta.2014.04.048

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Porous Cu-Ni alloys with a wide range of compositions have been deposited from citrate baths containing the two metal ions, under application,of large current densities (-3 A cm(-2)) leading to vigorous hydrogen evolution. The deposited alloy layers show macroscopic porosity and a spongy material made of a network of tiny dendrites. Porous RDEs reveal a significant current increase - as compared to ordinary polished electrodes - in the fast ferrocyanide reduction under pure mass transport control. Voltammograms of nitrate reduction in alkali at porous RDEs show at all potentials larger currents in comparison with experiments at compact electrodes of same composition. Electrolyses at porous sheet electrodes show large stable currents, leading to fast and selective nitrate reduction to ammonia. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：337 / 344

页数：8

共 52 条

[1] Preparation of arrays of isolated spherical cavities by self-assembly of polystyrene spheres on self-assembled pre-patterned macroporous films
Abdelsalam, ME
Bartlett, PN
Baumberg, JJ
Coyle, S
[J]. ADVANCED MATERIALS, 2004, 16 (01) : 90 - +
[2] Adam R. N., 1969, ELECTROCHEMISTRY SOL, P220
[3] Bard A.J., 1980, Electrochemical Methods: Fundamentals and Applications, V1st, P289
[4] Highly ordered macroporous gold and platinum films formed by electrochemical deposition through templates assembled from submicron diameter monodisperse polystyrene spheres
Bartlett, PN
Baumberg, JJ
Birkin, PR
Ghanem, MA
Netti, MC
[J]. CHEMISTRY OF MATERIALS, 2002, 14 (05) : 2199 - 2208
[5] ROTATED POROUS CARBON DISK ELECTRODE
BLAEDEL, WJ
WANG, J
[J]. ANALYTICAL CHEMISTRY, 1980, 52 (01) : 76 - 80
[6] On the behavior of the porous rotating disk electrode
Bonnecaze, Roger T.
Mano, Nicolas
Nam, Bomi
Heller, Adam
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (02) : F44 - F47
[7] Electrochemical reduction of nitrate in weakly alkaline solutions
Bouzek, K
Paidar, M
Sadílková, A
Bergmann, H
[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 2001, 31 (11) : 1185 - 1193
[8] THE ANALYSIS OF ELECTRODE IMPEDANCES COMPLICATED BY THE PRESENCE OF A CONSTANT PHASE ELEMENT
BRUG, GJ
VANDENEEDEN, ALG
SLUYTERSREHBACH, M
SLUYTERS, JH
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 176 (1-2): : 275 - 295
[9] ELECTROCHEMICAL REDUCTION OF NITROGEN OXYANIONS IN 1-M SODIUM-HYDROXIDE SOLUTIONS AT SILVER, COPPER AND CUINSE2 ELECTRODES
CATTARIN, S
[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1992, 22 (11) : 1077 - 1081
[10] Direct electrodeposition of nanoporous gold with controlled multimodal pore size distribution
Cherevko, Serhiy
Chung, Chan-Hwa
[J]. ELECTROCHEMISTRY COMMUNICATIONS, 2011, 13 (01) : 16 - 19

← 1 2 3 4 5 6 →