Field influence on the slow magnetic relaxation of nickel-based single ion magnets

被引：38

作者：

Titis, Jan ^{[1
]}

Rajnak, Cyril ^{[1
]}

Valigura, Dusan ^{[1
]}

Boca, Roman ^{[1
]}

机构：

[1] Univ SS Cyril & Methodius, Dept Chem, Fac Nat Sci, Trnava 91701, Slovakia

来源：

DALTON TRANSACTIONS | 2018年 / 47卷 / 24期

关键词：

MOLECULE MAGNET; ZERO-FIELD; ELECTRONIC-STRUCTURE; ENERGY BARRIER; COMPLEX; ANISOTROPY; NI(II);

D O I：

10.1039/c8dt01445k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A mononuclear Ni(ii) complex, [Ni(pydca)(dmpy)]H2O, pyridine-2,6-dicarboxylato-2,6-dimethanolpyridine nickel(ii) monohydrate, exhibits a slow magnetic relaxation under an applied magnetic field with two and/or three relaxation channels. While at B-DC = 0.2 T, the low-frequency relaxation mode is weakly developed, its intensity grows rapidly with the field so that at B-DC = 0.6 T, this is the dominating relaxation path giving rise to a relaxation time of (LF) = 322 ms at T = 2.0 K. At B-DC = 1.2 T the relaxation time is as slow as (LF) = 876 ms.

引用

页码：7879 / 7882

页数：4

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