Vibration-rotational interaction and doublet structure of the 390 cm-1 quasi-line in the fluorescence spectrum of anthracene vapors

被引：0

作者：

Demchuk, YS ^{[1
]}

Vandyukov, EA ^{[1
]}

机构：

[1] FSPC, GIPO, Kazan, Russia

来源：

13TH SYMPOSIUM AND SCHOOL ON HIGH-RESOLUTION MOLECULAR SPECTROSCOPY | 2000年 / 4063卷

关键词：

vibronic spectra; Coriolis interaction; vapor phase; anthracene; high temperatures;

D O I：

10.1117/12.375377

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

The report presents the results of the study of the intramolecular V-R Coriolis interaction between closely-spaced energy levels of a molecule with a certain symmetry of the wave functions corresponding to these levels using the anthracene molecule. As an example, the consideration of V-R interactions has been shown to result in the formation of doublet structure of the 390 cm(-1) quasi-line in the emission spectrum.

引用

页码：189 / 192

页数：4

共 16 条

[1] COOLING OF LARGE AND HEAVY MOLECULES IN SEEDED SUPERSONIC BEAMS [J].

AMIRAV, A ;

EVEN, U ;

JORTNER, J .

CHEMICAL PHYSICS, 1980, 51 (1-2) :31-42

[2] RESONANCE FLUORESCENCE OF AROMATIC MOLECULES IN VAPOR PHASE [J].

BLONDEAU, JM ;

STOCKBUR.M .

BERICHTE DER BUNSEN-GESELLSCHAFT FUR PHYSIKALISCHE CHEMIE, 1971, 75 (05) :450-+

[3]

BORISEVICH NA, 1989, OPT SPEKTROSK+, V67, P1293

[4]

DEMCHUK YS, 1988, OPT SPEKTROSK+, V65, P552

[5]

DEMCHUK YS, 1992, OPT SPEKTROSK+, V72, P876

[6]

DEMCHUK YS, 1981, J APPL SPECTROSC, V35, P641

[7]

GERZBERG G, 1969, ELECT SPECTRA STRUCT

[8]

KLOCHKOV VP, 1968, OPT SPEKTROSK, V24, P40

[9]

LAMBERT WR, 1984, J CHEM PHYS, V81, P2195, DOI [10.1063/1.447922, 10.1063/1.447923]

[10]

MIRUMYANTS SO, 1974, OPT SPEKTROSK+, V36, P90

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