A Germylene Stabilized by Homoconjugation

被引：36
作者：
Dong, Zhaowen [1 ]
Reinhold, Crispin R. W. [1 ]
Schmidtmann, Marc [1 ]
Mueller, Thomas [1 ]
机构：
[1] Carl von Ossietzky Univ Oldenburg, Inst Chem, Carl von Ossietzky Str 9-11, D-26129 Oldenburg, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 51期
关键词：
carbene analogues; germanium; homoconjugation; hyperconjugation; X-ray diffraction; TRANSITION-METAL-COMPLEXES; NATURAL RESONANCE THEORY; INITIO SCF-MO; CATIONIC METALLOGERMYLENE; INVERTED SEQUENCE; CRYSTAL-STRUCTURE; ELEMENTS; CHEMISTRY; REACTIVITY; AMIDES;
D O I：
10.1002/anie.201609576
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of a bicyclic germylene from the reaction of a germole dianion with hafnocene dichloride is reported. This germylene is stabilized by a homoconjugative interaction of the dicoordinated germanium atom with a remote C=C double bond. First reactivity studies revealed its nucleophilic character and resulted in the synthesis of bimetallic hafnium/iron and hafnium/tungsten complexes with a germylene group linker.
引用
收藏
页码：15899 / 15904
页数：6
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