Resonance Assisted Chalcogen Bonding as a New Synthon in the Design of Dyes

被引：55

作者：

Gurbanov, Atash, V ^{[1
,2
]}

Kuznetsov, Maxim L. ^{[1
]}

Mahmudov, Kamran T. ^{[1
,2
]}

Pombeiro, Armando J. L. ^{[1
]}

Resnati, Giuseppe ^{[3
]}

机构：

[1] Univ Lisbon, Ctr Quim Estrutural, Inst Super Tecn, Av Rovisco Pais, P-1049001 Lisbon, Portugal

[2] Baku State Univ, Dept Chem, Z Xalilov Str 23, AZ-1148 Baku, Azerbaijan

[3] Politecn Milan, Lab Nanostruct Fluorinated Mat NFMLab, Dept Chem Mat & Chem Engn Giulio Natta, Via L Mancinelli 7, I-20131 Milan, Italy

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2020年 / 26卷 / 65期

关键词：

chalcogen bonds; noncovalent interactions; synthesis; HYDROGEN-BONDS; CRYSTAL-STRUCTURE; LONE-PAIR; HALOGEN; SULFAMETHIZOLE; CATALYSIS; COMPLEXATION; TERMS;

D O I：

10.1002/chem.202002518

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intramolecular chalcogen bonding in arylhydrazones of sulfamethizole is strengthened by conjugation in the pi-system of a noncovalent five-membered ring. The S...O distance in the sulfamethizole moiety of these compounds ranges from 2.698(3) to 2.806(15) angstrom, which indicates its strong dependence on the attached arylhydrazone fragments. Information on the nature of the intramolecular chalcogen bond was afforded by DFT calculations.

引用

页码：14833 / 14837

页数：5

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