Synthesis of (azidomethyl)phenylboronic acids

被引:10
|
作者
Fedorov, AY
Shchepalov, AA
Bol'shakov, AV
Shavyrin, AS
Kurskii, YA
Finet, JP
Zelentsov, SV
机构
[1] NI Lobachevskii State Univ, Nizhnii Novgorod 603950, Russia
[2] Russian Acad Sci, GA Razuvaev Inst Organomet Chem, Nizhnii Novgorod 603600, Russia
[3] Aix Marseille Univ, Fac Sci St Jerome, F-13397 Marseille, France
基金
俄罗斯基础研究基金会;
关键词
azidomethylphenylboronic acids; synthesis; quantum-chemical calculations;
D O I
10.1023/B:RUCB.0000030813.05424.1f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of 2-, 3-, and 4-(azidomethyl)phenylboronic acids was carried out. The geometric and electronic structures were studied by quantum-chemical methods. The suggestion is made that there are weak intramolecular interactions between the boron atom and the nitrene nitrogen atom of the azido group.
引用
收藏
页码:370 / 375
页数:6
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