Growth of carbon nanotubes on the surface of carbon fiber using Fe-Ni bimetallic catalyst at low temperature

被引：33

作者：

Ma, Ziming ^{[1
,2
]}

Wang, Yanxiang ^{[1
,2
]}

Qin, Jianjie ^{[2
]}

Yao, Zhiqiang ^{[2
]}

Cui, Xuanhao ^{[2
]}

Cui, Bowen ^{[2
]}

Yue, Yang ^{[2
]}

Wang, Yongbo ^{[2
]}

Wang, Chengguo ^{[1
,2
]}

机构：

[1] Shandong Univ, Minist Educ, Key Lab Liquid Solid Struct Evolut & Proc Mat, 17923 Jingshi Rd, Jinan 250061, Peoples R China

[2] Shandong Univ, Sch Mat Sci & Engn, Carbon Fiber Engn Res Ctr, Jinan 250061, Peoples R China

来源：

CERAMICS INTERNATIONAL | 2021年 / 47卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Carbon fibers; Carbon nanotubes; Chemical vapor deposition; Tensile strength;

D O I：

10.1016/j.ceramint.2020.08.278

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

This article provides a method for growing carbon nanotubes(CNTs) on carbon fibers(CFs) using iron and nickel as catalysts at low temperatures. This series of experiments was conducted in a vacuum chemical vapor deposition(CVD)furnace. It is found that Fe-Ni catalysts, which have a certain thickness and can be better combined with resins when manufacturing composite materials, are more ideal for the growth of CNTs than single metal catalysts. At the same time, it is proved that the CVD process worked best at 450 degrees C. The mechanical property test proved the reinforcing effect of CNTs on carbon fiber, the single-filament tensile strength of CFs obtained by using Fe-Ni catalyst at 450 degrees C was 11% higher than that of Desized CFs. The bonding strength of carbon fiber and resin has also been significantly improved. When synthesized at low temperature, CNTs exhibited a hollow multi wall structure.

引用

页码：1625 / 1631

页数：7

共 45 条

[1] Effect of carbon nanotube length and density on the properties of carbon nanotube-coated carbon fiber/polyester composites [J].

Agnihotri, Prabhat ;

Basu, Sumit ;

Kar, K. K. .

CARBON, 2011, 49 (09) :3098-3106

[2] Preparation and characterization of carbon nanotube-hybridized carbon fiber to reinforce epoxy composite [J].

An, Feng ;

Lu, Chunxiang ;

Li, Yonghong ;

Guo, Jinhai ;

Lu, Xiaoxuan ;

Lu, Huibin ;

He, Shuqing ;

Yang, Yu .

MATERIALS & DESIGN, 2012, 33 :197-202

[3] Fabrication of Co-W Alloy/Multiwalled Carbon Nanotube Composite Films by Electrodeposition for Improved Frictional Properties [J].

Arai, Susumu ;

Miyagawa, Kazuaki .

ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY, 2013, 2 (11) :M39-M43

[4]

Ata S., 2014, SCI REP-UK, V4, P8

[5] Quantitative determination of size and properties of interphases in carbon nanotube-based multiscale composites [J].

Bedi, Harpreet S. ;

Tiwari, Mayank ;

Agnihotri, Prabhat K. .

CARBON, 2018, 132 :181-190

[6] Low temperature growth of carbon nanotubes on tetrahedral amorphous carbon using Fe-Cu catalyst [J].

Cartwright, R. ;

Esconjauregui, S. ;

Hardeman, D. ;

Bhardwaj, S. ;

Weatherup, R. ;

Guo, Y. ;

D'Arsie, L. ;

Bayer, B. ;

Kidambi, P. ;

Hofmann, S. ;

Wright, E. ;

Clarke, J. ;

Oakes, D. ;

Cepek, C. ;

Robertson, J. .

CARBON, 2015, 81 :639-649

[7] The effect of double grafted interface layer on the properties of carbon fiber reinforced polyamide 66 composites [J].

Chen, Jinchuan ;

Xu, Huajie ;

Liu, Chuntai ;

Mi, Liwei ;

Shen, Changyu .

COMPOSITES SCIENCE AND TECHNOLOGY, 2018, 168 :20-27

[8] Effect of carbon fibers grafted with carbon nanotubes on mechanical properties of cement-based composites [J].

Cui, Hongzhi ;

Jin, Zhiyang ;

Zheng, Dapeng ;

Tang, Waiching ;

Li, Yubo ;

Yun, Yanchun ;

Lo, Tommy Yiu ;

Xing, Feng .

CONSTRUCTION AND BUILDING MATERIALS, 2018, 181 :713-720

[9] Direct growth of carbon nanotubes on carbon fibers: Effect of the CVD parameters on the degradation of mechanical properties of carbon fibers [J].

De Greef, Niels ;

Zhang, Luman ;

Magrez, Arnaud ;

Forro, Laszlo ;

Locquet, Jean-Pierre ;

Verpoest, Ignaas ;

Seo, Jin Won .

[10] Effects of grafting strength and density on interfacial shear strength of carbon nanotube grafted carbon fibre reinforced composites [J].

Deng, Yan ;

Islam, Mohammad S. ;

Tong, Liyong .

COMPOSITES SCIENCE AND TECHNOLOGY, 2018, 168 :195-202

← 1 2 3 4 5 →