Pyrolysis of solid waste residues from Lemon Myrtle essential oils extraction for bio-oil production

被引:77
作者
Abu Bakar, Muhammad S. [1 ]
Ahmed, Ashfaq [1 ,2 ,3 ]
Jeffery, Deane M. [1 ]
Hidayat, Syarif [1 ,4 ]
Sukri, Rahayu S. [5 ]
Mahlia, Teuku Meurah Indra [6 ]
Jamil, Farrukh [3 ]
Khurrum, Muhammad Shahzad [3 ]
Inayat, Abrar [7 ]
Moogi, Surendar [2 ]
Park, Young-Kwon [2 ]
机构
[1] Univ Brunei Darussalam, Fac Integrated Technol, Jalan Tungku Link, BE-1410 Bandar Seri Begawan, Brunei
[2] Univ Seoul, Sch Environm Engn, Seoul 02504, South Korea
[3] COMSATS Univ Islamabad, Dept Chem Engn, Lahore Campus,Raiwind Rd, Lahore 54000, Punjab, Pakistan
[4] Univ Banten Jaya, Dept Environm Engn, Serang 42121, Banten, Indonesia
[5] Univ Brunei Darussalam, Fac Sci, Environm & Life Sci Programme, Jalan Tungku Link, BE-1410 Bandar Seri Begawan, Brunei
[6] Univ Technol Sydney, Fac Engn & Informat Technol, Sch Syst Management & Leadership, Sydney, NSW 2007, Australia
[7] Univ Sharjah, Dept Sustainable & Renewable Energy Engn, Sharjah, U Arab Emirates
基金
新加坡国家研究基金会;
关键词
Solid waste residue; Lemon myrtle; Biorefinery; Pyrolysis; Bio-oil; BIOMASS; LIGNIN; HEMICELLULOSE; CELLULOSE;
D O I
10.1016/j.biortech.2020.123913
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Solid waste residues from the extraction of essential oils are projected to increase and need to be treated appropriately. Valorization of waste via pyrolysis can generate value-added products, such as chemicals and energy. The characterization of lemon myrtle residues (LMR) highlights their suitability for pyrolysis, with high volatile matter and low ash content. Thermogravimetric analysis/derivative thermogravimetric revealed the maximum pyrolytic degradation of LMR at 335 degrees C. The pyrolysis of LMR for bio-oil production was conducted in a fixed-bed reactor within a temperature range of 350-550 degrees C. Gas chromatography-mass spectrometry showed that the bio-oil contained abundant amounts of acetic acid, phenol, 3-methyl-1,2-cyclopentanedione, 1,2-benzenediol, guaiacol, 2-furanmethanol, and methyl dodecanoate. An increase in pyrolysis temperature led to a decrease in organic acid and ketones from 18.09% to 8.95% and 11.99% to 8.75%, respectively. In contrast, guaiacols and anhydrosugars increased from 24.23% to 30.05% and from 3.57% to 7.98%, respectively.
引用
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页数:5
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